Question

In: Chemistry

. Consider this reaction: zinc metal reacts with hydrochloric acid to produce hydrogen and zinc chloride....

. Consider this reaction: zinc metal reacts with hydrochloric acid to produce hydrogen and zinc chloride.

Zn + 2 HCl → ZnCl2 + H2

(a) If 0.30 mol of Zn is added to hydrochloric acid containing 0.52 mol of HCl, how many moles of H2 are produced? (or what is the theoretical yield of H2 produced in the reaction?)

(b) In the above procedure, if the actual yield of the reaction is 0.26 mol of H2. What is the percent yield of the reaction?

(c ) If another piece of 12.46g sample of zinc reacts with excess HCl to form 0.298g of H2. How pure is the zinc?

Solutions

Expert Solution

a)

Zn + 2 HCl   ---------->   ZnCl2 +    H2

1         2                             1             1

0.30     0.52

here limiting reagent = HCl .

2 mol HCl   ----------->   1 mol H2

0.52 mol HCl   ----------> ??

moles of H2 = 0.52 x 1 / 2 = 0.26

moles of H2 produced = 0.26

b)

actual yield = 0.26 mol

percent yield = (actual / theoretical) x 100

                      = (0.26 / 0.26) x 100

percent yield = 100 %

c)

mass of zn sample = 12.46 g

moles of Zn = 12.46 / 65.38 = 0.1905

Zn    + 2 HCl   ---------->   ZnCl2 +    H2

65.38 g     72.92 g                                   2.00 g

12.46 g                                                      ??

mass of H2 = 12.46 x 2 / 65.38

                    = 0.381 g

percent yield = (0.298 / 0.381) x 100

                      = 78.2 %


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