Question

In: Chemistry

a solution is initially 0.0884 M in an acid which is 21.4% ionized at equilibrium. Calculate...

a solution is initially 0.0884 M in an acid which is 21.4% ionized at equilibrium. Calculate the Ka for the solution at 25C (assume all acids are monoprotic)

Solutions

Expert Solution

Let the given monoprotic acid be represented by HX.

HXH+ +X- [equilibrium]

ICE table

                [HX]                [H+]               [X-]

initial             0.0884M          0                    0

change        -0.0884*0.25=-0.0221M               +0.0221M           +0.0221M

equilibrium    0.0884-0.0221=0.0663M               0.0221M            0.0221M

ka=equilibrium constant=[H+][X-]/[HX]=(0.0221M)(0.0221M)/(0.0663M)=0.00737M

ka=0.00737M


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