Question

In: Chemistry

consider the reaction between Mg(s) and HCl(aq) to producer aqueous magnesium chloride and hydrogen gas. How...

consider the reaction between Mg(s) and HCl(aq) to producer aqueous magnesium chloride and hydrogen gas. How many liters of hydrogen gas at STP will be produced when 12.15 g of magnesium reacts with an excess of hydrochloric acid?

Solutions

Expert Solution

a) Let's first calculate # of moles of Mg (s) in 12.15 g of Mg.

# of Moles of Mg = Given Mass of Mg / Atomic Mass of Mg = 12.15 g / 24.30 g/moles = 0.5 moles.

A pertinent equation for the reaction between Mg (s) & HCl (aq) is,

Mg (s) + 2 HCl (aq) MgCl2 (aq) + H2 (g).

A mole equivalence for the reaction is,

1 mole of Mg (s) 1 mole of H2 (g).

0.5 mole of Mg (s) 0.5 mole of H2 (g).

Theoretically, on the complete reaction of 12.15 g (i.e 0.5 mole) Mg, 0.5 (i.e. 1/2 or half) moles of H2 (g) will be produced.

According to the Avogadro's Hypothesis, at STP, 1 mole of n ideal gas occupies 22.414 L of the volume.

Assuming H2 (g) as an Ideal gas,

0.5 moles of H2 (g) will occupy 22.414 / 2 = 11.207 L of the volume.

Volume occupied at STP is 11.207 L.

Answer: 11.207 L of hydrogen gas at STP will be produced when 12.15 g of magnesium reacts with an excess of hydrochloric acid.

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