In: Chemistry
What is the total amount of heat required (in kJ) to convert 192 g of ice at -17 oC into steam at 122 oC?
Sp. Heat for ice = 2.09 J/goC
Sp. Heat for water = 4.18 J/goC
Sp. Heat for steam = 1.84 J/goC
ΔHfus = 6.01 kJ/mol
ΔHvap = 40.67 kJ/mol
Given that;
Amount of ice = 192 g
Initial temperature = -17 oC
Final temperature = 122 oC
Sp. Heat for ice = 2.09 J/goC
Sp. Heat for water = 4.18 J/goC
Sp. Heat for steam = 1.84 J/goC
ΔHfus = 6.01 kJ/mol
ΔHvap = 40.67 kJ/mol
Step I:
Freezing point of ice= 0.0oC
So temperature change
Heating the ice:
∆T = 0 - (-17) = 17 C
We know that q = = M* cp *dT
Here m = mass of ice
cp = specific heat
dT = temperature change
q = 192 g x 2.09 J/g*C x 17 = 6821.76 J
step II:
Melting the ice:
in this process; Temperature not required, since it's a phase
change from solid to liquid at constant temperature.
q = 192g/18g/mole x 6.01 kJ/mo * 1000 J / 1 kJ = 64106.67
J
step III:
Heating the water:
∆T = 100 - 0 = 100 C
q = 192g x 4.18 J/g*C x 100 C = 80256 J
Step IV:
Vaporizing the water:
similar in this process; Temperature not required, since it's a
phase change from liquid to gas at constant temperature.
q = 192 g/18g/mole x 40.67 kJ/mol * 1000 J / 1kJ = 433813.33
J
step V:
Heating the steam :
∆T = 122 - 100 = 22 C
q = 192 g x 2.09 J/g*C x 22 C = 8828.16 J
q(total) = 6821.76 + 64106.67 + 80256 + 433813.33 + 8828.16 =
593825.92J
593825.92 J * 1 .00 Kj /1000 J
= 593.83 KJ