Question

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1. In order to evaluate a spectrophotometric method for the determination of titanium, the method was...

1. In order to evaluate a spectrophotometric method for the determination of titanium, the method was applied to alloy samples containing difference certified amounts of titanium. The results (%Ti) are shown below.

Sample                        Certified Value           Mean               Standard Deviation

1                      0.496                           0.482               0.0257

2                      0.995                           1.009               0.0248

3                      1.493                           1.505               0.0287

4                      1.990                           2.002               0.0212

For each alloy, eight replicate determinations were made. For each alloy, test whether the mean value differs significantly from the certified value.

Solutions

Expert Solution

Sample 1:

Data:    

n = 8   

μ = 0.496   

s = 0.0257   

x-bar = 0.482   

Hypotheses:   

Ho: μ = 0.496   

Ha: μ ≠ 0.496   

Decision Rule:   

α = 0.05   

Degrees of freedom = 8 - 1 = 7

Lower Critical t- score = -2.364624251

Upper Critical t- score = 2.364624251

Reject Ho if |t| > 2.364624251

Test Statistic:   

SE = s/√n = 0.0257/√8 = 0.009086322

t = (x-bar - μ)/SE = (0.482 - 0.496)/0.00908632213824714 = -1.54078

p- value = 0.167269951   

Decision (in terms of the hypotheses):

Since 1.540777422 < 2.364624 we fail to reject Ho

Conclusion (in terms of the problem):

This sample meets the certified value

Sample 2:

Data:    

n = 8   

μ = 0.995   

s = 0.0248   

x-bar = 1.009   

Hypotheses:   

Ho: μ = 0.995   

Ha: μ ≠ 0.995   

Decision Rule:   

α = 0.05   

Degrees of freedom = 8 - 1 = 7

Lower Critical t- score = -2.364624251

Upper Critical t- score = 2.364624251

Reject Ho if |t| > 2.364624251

Test Statistic:   

SE = s/√n = 0.0248/√8 = 0.008768124

t = (x-bar - μ)/SE = (1.009 - 0.995)/0.00876812408671319 = 1.596693

p- value = 0.15436533   

Decision (in terms of the hypotheses):

Since 1.596692732 < 2.364624 we fail to reject Ho

Conclusion (in terms of the problem):

This sample meets the certified value

Sample 3:

Data:    

n = 8   

μ = 1.493   

s = 0.0287   

x-bar = 1.505   

Hypotheses:   

Ho: μ = 1.493   

Ha: μ ≠ 1.493   

Decision Rule:   

α = 0.05   

Degrees of freedom = 8 - 1 = 7

Lower Critical t- score = -2.364624251

Upper Critical t- score = 2.364624251

Reject Ho if |t| > 2.364624251

Test Statistic:   

SE = s/√n = 0.0287/√8 = 0.010146982

t = (x-bar - μ)/SE = (1.505 - 1.493)/0.010146982310027 = 1.182618

p- value = 0.275567805   

Decision (in terms of the hypotheses):

Since 1.182617613 < 2.364624 we fail to reject Ho

Conclusion (in terms of the problem):

This sample meets the certified value

Sample 4:

Data:    

n = 8   

μ = 1.99   

s = 0.0212   

x-bar = 2.002   

Hypotheses:   

Ho: μ = 1.99   

Ha: μ ≠ 1.99   

Decision Rule:   

α = 0.05   

Degrees of freedom = 8 - 1 = 7

Lower Critical t- score = -2.364624251

Upper Critical t- score = 2.364624251

Reject Ho if |t| > 2.364624251

Test Statistic:   

SE = s/√n = 0.0212/√8 = 0.007495332

t = (x-bar - μ)/SE = (2.002 - 1.99)/0.0074953318805774 = 1.600996

p- value = 0.153411302   

Decision (in terms of the hypotheses):

Since 1.600996486 < 2.364624 we fail to reject Ho

Conclusion (in terms of the problem):

This sample meets the certified value.


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