1) In H NMR spectroscopy, why is the peak for a vinyl proton,
C=C-H, shifted downfield relative to that of an alkane proton,
C(sp3)-H? Be sure to use the following terms in your
answer: pi-electrons, induced magnetic field, and resonance.
2) In H NMR spectroscopy, why is the peak for a
-CH2F group shifted downfield relative to that for a
-CH2Br group? Be sure to use the following terms in your
answer: electronegative, deshielded, magnetic field, and
frequency.