In: Mechanical Engineering
1.What are the distinctive features between a polyester and vinyl ester in terms of their properties.
2.List five (5) general characteristics of fiber re-enforced composites over their metal counterparts.
please no hand writing.
polyester | vinyl ester |
Polyester resins are formed by the reaction between polyols such as glycol or ethylene glycol with dibasic acids such as phthalic acid or maleic acid. | Vinyl ester resins are produced by the reaction ('esterification') between an epoxy resin and an unsaturated monocarboxylic acid. |
These unsaturated resins are combined with other chemicals sometimes called hardeners or catalysts.Methyl ethyl ketone peroxide ('MEKP') is one such 'hardening' agent. | Essentially they comprise a base of polyester resin strengthened with epoxy molecules in the backbone of the molecular chain.Vinyl esters also use peroxides (e.g. MEKP) for hardening. |
polyesters have High Viscosity | vinyl esters are midway between polyesters and epoxy resins in terms of Viscosity |
polyesters are less tolerant of stretching than Vinyl esters. | Vinyl esters are more tolerant of stretching than polyesters.This makes them more able to absorb impact without damage. They are also less likely to show stress cracking. |
polyesters shrink more on curing |
Vinyl esters shrink less on curing, which means that 'pre-release' of a laminate from a mold is less significant. |
polyesters are stronger resistance to ambient conditions | Vinyl esters are less sensitive to ambient conditions (temperature and humidity) than are polyesters |
The cross bonding of polyesters. is less superior to that of vinyl esters | The cross bonding of vinyl esters is superior to that of polyesters. |
polyesters are cheaper than Vinyl esters | Vinyl esters are more expensive than polyesters |
2) Some key characteristics of composites that make them so useful are:
1) Specific strength : This is simply the rigidity or hardness of a material with regard to its weight. For example, a number of composites such as fiberglass share comparable impact resistance (bangability) with steel and titanium at a fraction of the weight employed.
2) Expense:Many composites can be manufactured with less cost than their traditional metal counterparts.
3)Application : Because composites are composed of 2 or more "phases", they can be formulated to meet the needs of a specific application with considerable ease.
4) Processability : As most of you know, metal processing requires high amounts of thermal energy (heat). Plastics and plastic based composites require less heat to mold or process the products.
5) Bonding/Blending of composites
general Charactersistics :
Amount of Fibres
Orientation of Fibres
Types of Fibres
Fiber Aspect Ratio
Fibre Orientation Effect
Strain rate effects
Type Of matrix
Interfacial Bonding Conditions