Question

In what ways do the minerals in the discontinuous series differ from each other? And the minerals in the continuous series?

Answer 1

These two examples illustrate two principal reactions that occur during crystallization of common magmas, one discontinuous (the olivine-liquid-pyroxene reaction) and the other continuous (the plagioclase-liquid reaction). This was recognized first by the American petrologist Norman L. Bowen, who arranged the reactions ; in his honour, the mineral series has since been called the Bowen’s reaction series. The left branch of the Y-shaped arrangement consists of the discontinuous series that begins with olivine at the highest temperature and progresses through pyroxene, amphibole, and biotite as the temperature decreases. This series is discontinuous because the reaction occurs at a fixed temperature at constant pressurewherein the early-formed mineral is converted to a more stable crystal. Each mineral in the series displays a different silicate structure that exhibits increased polymerization as the temperature drops; olivine belongs to the island silicate structure type; pyroxene, the chain; amphibole, the double chain; and biotite, the sheet. On the other hand, the right branch is the continuous reaction series in which plagioclase is continuously reacting with the liquid to form a more albitic phase as the temperature decreases. In both cases, the liquid is consumed in the reaction. When the two reaction series converge at a low temperature, minerals that will not react with the remaining liquid approach eutectic crystallization. Potash feldspar, muscovite, and quartz are crystallized. The phases that are crystallized first are the common minerals that compose basalt or gabbro, like bytownite or labradorite with pyroxene and minor amounts of olivine. Andesite or diorite minerals, such as andesine with either pyroxene or amphibole, crystallize next and are followed by orthoclase and quartz, which are the essential constituents of rhyolite or granite. A basaltic liquid at the top of the Ycan descend to the bottom of the series to crystallize quartz only if the earlier reactions are prevented. As demonstrated above, complete reactions between early-formed minerals and the liquid depletes the supply of the liquid, thereby curtailing the progression down the series. One means by which basaltic magma can be transformed to rocks lower in the series is by fractional crystallization. In this process, the early-formed minerals are removed from the liquid by gravity (such minerals as olivine and pyroxene are denser than the liquid from which they crystallized), and so unreacted liquid remains later in the series.Another method of creating different daughter magmas from a parent is by having the latter react with its wall rocks. Consider a magma that is crystallizing pyroxene and labradorite. If the magma tears from its wall minerals, say, olivine and anorthite, which are formed earlier than pyroxene and labradorite in the series, they will react with the liquid to form these same minerals with which the magma is in equilibrium. The heat for driving this reaction comes directly from the magma itself. More pyroxene and labradorite will crystallize during the reaction and will release their latent heats of crystallization. On the other hand, if a mineral (quartz, for example) formed at a later stage than pyroxene or labradorite falls from the rock wall into the magma, the latent heat provided by further crystallization of pyroxene and labradorite will cause it to dissolve. This situation will occur only if the quartz from the wall rock is at a lower temperature than the magma. It will cause the magma to transfer its heat to the quartz in a cooling process. The cooling of the magma will necessarily be accompanied by the crystallization of the minerals already present. In both cases, the composition of the parent magma will be changed by the xenolithic (foreign rock) contamination. The contaminant need not belong to the reaction series in order for it to cause reactions or dissolution. In most cases, the end result will be a shift from the original composition of the parent magma toward that of the contaminant. This process in which wall rocks are incorporated into the magma is called assimilation. Because assimilation is accompanied by crystallization, it is likely that both fractional crystallization and assimilation will take place simultaneously. This combined process, referred to as AFC for assimilation–fractional crystallization, has been proposed as the mechanism by which andesites are produced from basalts.

Water and most other volatile substances profoundly influence the properties and behaviour of magmas in which they are dissolved. They reduce viscosity, lower temperatures of crystallization by tens to hundreds of degrees, and participate directly in the formation of minerals that contain essential hydroxyl (OH) or elements such as the halogens. They also increase rates of crystallization and reaction, especially when they are present as a fluid phase distinct from the magma. In general, however, they have only a limited influence on the sequence of magmatic crystallization, except in the latest stages of the reaction series.

The relatively low confining pressures in volcanic environments permit ready escape of volatile constituents, which nonetheless leave their imprint in the form of special mineral assemblages and a variety of textural and structural features among the volcanic rocks. Under the higher pressures of plutonic environments, these constituents tend to be maintained in magmatic solution and to be increasingly concentrated as crystallization progresses with falling temperature. Few members of the reaction series require them as compositional contributors; water, for example, is not thus used until amphiboles or micas begin to form, and even then the amounts removed from the melt rarely are large. Escape of volatiles from the system can occur “osmotically” if the enclosing rocks are pervious to them but not to the magma, but in general they are fractionated in favour of the residual melt until their concentration reaches the limit of solubility under the prevailing conditions of temperature and effective confining pressure. When this happens, normally at a very late stage of magmatic crystallization, they are exsolved from the melt as a separate fluid phase that under most circumstances is a supercritical gas. This process has been referred to as resurgent boiling, a somewhat misleading term because the exsolved fluid is not necessarily expelled from the system.

Coexistence of residual magma and a volatile-rich fluid (generally aqueous) promotes the partitioning and segregation of constituents, as well as the growth of very large crystals. The exsolved fluid, with its very low viscosity, not only can move readily through open spaces in the nearly solid igneous rock and in adjacent rocks but also serves as a medium through which various substances can diffuse rapidly in response to concentration gradients. Thus, it plays an important role in the formation of such special rock types as the pegmatites and lamprophyres, special features such as miaroles and plumose mineral aggregates, and many kinds of ore deposits whose constituents are derived from the original magma.

Most plutonic systems remain at elevated temperatures for long periods of time after all magma has been used up, and during these periods hydrothermalconditions normally obtain. These depend upon the continued presence of a typically aqueous fluid that further facilitatescrystallization and exchanges of materials. It speeds up exsolution within homogeneous solid phases and devitrification of any glass that may be present, and it is a potent agent in the alteration, leaching, and replacement of minerals. Rock textures thereby are modified, especially along boundaries between original mineral grains, and details of composition also can be much changed. In some instances the bulk chemistry of the rock is markedly affected.

The hydrothermal alterations favour development of phases such as albite, carbonates, chlorites, clay minerals, epidotes, iron oxides, micas, silica minerals, talc, and zeolites, and many of them are accompanied by gross changes in volume.

Forms Of Occurrence

Extrusive igneous rocks

Extrusive igneous rocks are the products of volcanic activity. They appear at the surface as molten lava that spreads in sheets and hardens, or they are made up of fragments of magma ejected from vents by violent gaseous explosions. Large-scale extrusive features include stratovolcanoes (composite cones), shieldvolcanoes, lava domes, and cindercones. Smaller extrusive features include lava flows known as pahoehoe and aa. For a detailed description of the principal forms of extrusive igneous rocks, see volcano: Volcanic landforms: Major types of volcanic landforms

Intrusive igneous rocks

Erosion of volcanoes will immediately expose shallow intrusive bodies such as volcanic necks and diatremes (see Figure 6). A volcanic neck is the “throat” of a volcano and consists of a pipelike conduit filled with hypabyssal rocks. Ship Rock in New Mexico and Devil’s Tower in Wyoming are remnants of volcanic necks, which were exposed after the surrounding sedimentary rocks were eroded away. Many craterlike depressions may be filled with angular fragments of country rock(breccia) and juvenile pyroclastic debris. When eroded, such a depression exposes a vertical funnel-shaped pipe that resembles a volcanic neck with the exception of the brecciated filling. These pipes are dubbed diatremes. Many diatremes are formed by explosion resulting from the rapid expansion of gas—carbon dioxide and water vapour. These gases are released by the rising magmaowing to the decrease in pressureas it nears the surface. Some diatremes contain kimberlite, a peridotite that contains a hydrous mineral called phlogopite. Kimberlite may contain diamonds

Dikes are usually tabular bodies that may radiate from the central vent of a volcano or from a volcanic neck . Not all dikes are associated with volcanoes, but they can be distinguished by their discordant relationship with the structure of the country rock that they cut across. Many dikes are only a few metres wide, but large ones, such as the dike that feeds the Muskox intrusion in the Northwest Territories of Canada, reach widths of more than 150 metres. Related to dikes are features that maintain a concordant relationship with the structure of the country rocks. Magmas may force their way between layers of country rock and solidify parallel to them to form sills . On the west bank of the Hudson River opposite New York City, the 300-metre-thick Palisades sill is exposed and can be traced for 80 kilometres. A laccolith also is concordant with country rock, but it is distinguished from a sill by having a flat floor with a domed (mushroom-shaped) roof (see Figure 6). Laccoliths were first described in the Henry Mountainsof Utah, where they may measure up to 200 metres thick with basal diameters exceeding three kilometres. Rocks of intermediate silica content generally make up these domed intrusions. In contrast, lopoliths are saucer-shaped bodies with a concave upward roof and floor and are commonly composed of mafic rocks. Lopoliths are huge in size; the Bushveld intrusive complex in South Africa, for example, has an area of about 66,000 square kilometres and an exposed thickness of 8 kilometres. The Muskox intrusion, mentioned above, is another large lopolith, which is estimated to be about 80 kilometres long and 11 kilometres wide (roof rocks covering part of the intrusion prevent an exact measurement). These lopoliths are commonly layered with igneous minerals and rocks; in the Bushveld intrusion, one layer about 1 metre thick consisting of almost pure chromite (an ore of chromium) extends for tens of kilometres. Large irregularly shaped plutons are called either stocks or batholiths , depending on their sizes. Plutons larger than 100 square kilometres in area are termed batholiths, while those of lesser size are called stocks. It may be possible, however, that some stocks are the visible portions of batholiths that have not been exposed by erosion. Batholiths (from the Greek word bathos, meaning depth) are deep-seated crustal intrusions, whereas stocks may be formed at shallow depths only a few kilometres below the surface. Rocks ranging from quartz diorite to granite are commonly found in batholiths. Large batholiths in North Americainclude the Sierra Nevada, the Idaho, and the Coast Range, which is about 600 kilometres long and 200 kilometres wide and extends from the Alaskan border through British Columbia to Washington state. Many pulses of intrusions contribute to the formation of these large bodies; for example, eight episodes of activity have been recognized in the Sierra Nevada batholith. They are formed, therefore, by the coalescence of many smaller batholiths and stocks.

Distribution of igneous rocks on Earth’s surface

Divergent plate boundaries

Most of the igneous activity on Earth is restricted to a narrow zone that is related intimately with the motions of the lithospheric plates. Indeed, the composition of the magma, the types of volcanism, and the characteristics of intrusions are governed to a large extent by plate tectonics. The magmatism at divergent plate boundaries along the crests of the oceanic rises and ridges is mostly unseen except in places where the volcanic activity occurs subaerially (e.g., Iceland, which sits on the Mid-Atlantic Ridge). Along these divergent boundaries, the erupted basalts have such a restricted compositional range that they are referred to as mid-ocean-ridge basalt (MORB). They are subalkaline tholeiites that contain olivine in the norm and less than 0.25 percent potash. The chemistry suggests that MORB was generated from a mantle that was depleted of volatile elements (e.g., lanthanum [La], cerium [Ce], sodium, and potassium) in a previous partial melting process. A wide rift valley marks the crest of most of the oceanic ridges and rises. The valley is bounded by faults created by the divergent forces and is floored in its centre by a fracture zone (a mass of rock with many small breakages). These faults and fractures are the conduits for the MORB magmas that flood the valley, build volcanoes, and produce dikes by filling the conduits. Layer 2 of the oceanic crust results from these magmatic activities. As the plates diverge, MORB becomes the ocean floor on which oceanic sediments (layer 1) are deposited. This makes MORB the most abundant rock on the surface of Earth.

In older areas of convergence, the composite volcanoes have been eroded, exposing the deeper plutonic granite batholiths that extend the entire length of the convergent boundaries. The batholiths are predominantly granodiorite, but gabbro through granite occur as well. It seems anomalous to find diorite, the plutonic equivalent of andesite, in low abundance since andesite is the dominant rock type of the volcanoes that were above these batholiths. Two basic types of granite have been recognized. The more common variety is located closer to the trench, has hornblende as its mafic mineral, is enriched in sodium and calcium, and has mantle chemical signatures; it is called I-type granite. The other type, called S-type granite, has muscovite and biotite and is depleted in sodium but enriched in aluminum such that corundum occurs in the norm and isotopic signatures. This suggests that such granites were formed by partial fusion of sedimentary rocks.

Flood basalts

On the continental plates at areas away from active convergence, the magmatism is confined to rift valleys and local hot spots. The volume of magma produced is minor in comparison to that generated at oceanic rises and at convergent plate boundaries. Flood basalts are the most common form of occurrence. They span the rock record from the Precambrian to the Neogene Period (from about 4.6 billion to 2.6 million years ago) and are found worldwide. The 1.1-billion-year-old Keweenawan flood basalts in the Lake Superior region of northern Michigan may have formed in a rift that failed. The rifting of Pangaea that began during Jurassic time (approximately 200 million to 146 million years ago) generated flood basalt eruptions all along the newly opened Atlantic Ocean. Two voluminous eruptions associated with the opening of the South Atlantic produced the Paraná basalt in Brazil and the Karoo (or Karroo) in South Africa. The Deccan basalts in India were formed in the rift valleys associated with the breakup of Gondwana during the Cretaceous Period (approximately 146 million to 65.5 million years ago). Chemically, the most abundant basalts are supersaturated tholeiites with normative quartz, but olivine tholeiites and alkali basalts also are found. Feeder dikeswarms (groups consisting of many parallel dikes) and sills are common in flood basalt plateaus. Alkaline rocks, such as those found in the East African Rift System, occur as well but are less abundant. This rift system stretches southward from the Red Sea–Gulf of Aden to Lake Victoria. Undersaturated basalts are most common in these rifts. During one eruption, a magma composed mostly of sodium carbonate issued from a volcanic vent that had been erupting alkali basalts

Other terrestrial occurrences

Other diverse and unusual igneous rocks are found in the stable continental areas far from plate boundaries. These include the large layered basaltic intrusions—namely, the Stillwater Complex in Montana, the Muskox intrusion in the Northwest Territories of Canada, the Bushveld Complex in South Africa, and the Skaergaard intrusion in eastern Greenland. Tholeiitic magma underwent a fractional crystallization process that deposited layers of ultramafic rocks overlain by gabbroic and anorthositic layers. The end products of this fractionation are quartz- and feldspar-bearing rocks with a peculiar texture (known as graphic intergrowth) in which quartz and feldspar are intimately intergrown with each other. These rocks are called granophyres. Such layered intrusions have some economic importance; some of them contain thick (a few metres) layers of chromite, which is the source of chromium and also platinum. Two other rare occurrences in cratonic (stable) areas of Earth’s crust are the kimberlites and carbonatites. Both are of economic value because they yield diamonds and niobium, respectively. Kimberlites are micaperidotites that are found in pipes. The stable interiors of South Africa and Siberia have widespread occurrences, but these pipes also are found in North America, Australia, Brazil, and India. In North America, near Murfreesboro, Ark., individuals can pay a fee to search for diamonds in the Prairie Creek kimberlite pipe located in the Crater of Diamonds State Park. Not all kimberlites contain diamonds. When diamonds do occur, they constitute less than one part per million of the rock. Carbonatites are igneous rocks rich in carbonate (containing at least 50 percent) that commonly occur in ring complexes in association with other silica-poor rocks such as nepheline syenites. In North America, carbonatites have been found in dozens of localities in northern Ontario and western Quebec.

Extraterrestrial occurrences

The dominant igneous rock on Earth’s surface is basalt. It appears that such is also the case on Earth’s close neighbours. The lunar maria are covered with basalt lava flows. These lunar basalts have a mineralogy similar to that of terrestrial basalts, but chemically they have no water, a lower amount of alkalis and alumina, and a higher iron oxide and chromium content. On the lunar highlands, plagioclase-rich rocks are most common; these include anorthosites, gabbros, troctolites (olivine-plagioclase rock), and minor basalt. It appears that basalt is common on Mars as well. The large shield volcano Olympus Mons must have been formed from eruptions of fluid basalt flows. The X-ray fluorescence analyses performed by the Vikings 1 and 2 landers showed that the rocks are basaltic. In contrast, compositions of meteorites that originated from Mars include both basalts and ultramafic rocks such as dunite, clinopyroxenite, and iherzolite. The Mars Pathfinder and Rover show that andesite may also be present, but that result is still debated. Venus apparently has volcanic features with granitic to basaltic compositions.