Question

In: Chemistry

At equilibrium, this acid is found primarily in the water and not in the toluene. ....

At equilibrium, this acid is found primarily in the water and not in the toluene.

.   

At equilibrium, this acid is found primarily in the toluene and not in the water.

  

This acid has an almost equal affinity for water and for toluene.

Choices between Caproic , Acetic, and Butryic acid.

Solutions

Expert Solution

First let us identify the molecules:

Caproic --> CH3(CH2)4COOH --> this is the LEAST polar, actually could be considered nonpolar, since it has a very long chain, the dipoles are not strong enoguh

Acetic acid --> CH3COOH; this is the MOST polar, since it has a shor carbon/hydrogne chain vs. the COOH group

Butryic acid --> CH3(CH2)2COOH --> this has medium polarity.

Now, compare arguments

At equilibrium, this acid is found primarily in the water and not in the toluene. Like dissolves like, therefore, water a polar molecule, will dissolve with acetic acid mostly. Expect most acetic acid in the aqueous layer.

At equilibrium, this acid is found primarily in the toluene and not in the water. Like dissolves like, therefore, toluen, a nonpolar molecule, will dissolve with Caproic acid mostly. Expect most Caproic acid in the organic layer.

This acid has an almost equal affinity for water and for toluene. This is the "medium" species. Expect similar amounts in both, organic and aqueous layer. Butryic acid.


Related Solutions

a) The water in a lake is found to have a toluene concentration of 1 µg/L....
a) The water in a lake is found to have a toluene concentration of 1 µg/L. Calculate the concentration at equilibrium in the air above the lake (µg/L) and the sediment in the lake (µg/kg). Assume that the sediment has an organic carbon fraction of 0.05. b) Perform the same calculation for a phenanthrene concentration in water of 1 µg/L. c) For each chemical, comment on whether you would be more concerned about its release to the air or sediment....
Carbon dioxide dissolves in water to form carbonic acid, which is primarily dissolved CO2. Dissolved CO2...
Carbon dioxide dissolves in water to form carbonic acid, which is primarily dissolved CO2. Dissolved CO2 satisfies the equilibrium equation.The acid dissociation constants listed in most standard reference texts for carbonic acid actually apply to dissolved CO2. For a CO2 partial pressure of 3.2×10–4 bar in the atmosphere, what is the pH of water in equilibrium with the atmosphere? (For carbonic acid Ka1 = 4.46× 10–7 and Ka2 = 4.69× 10–11).
Trichloroacetic acid dissociates partially in water according to the equilibrium below. What is the percentage of...
Trichloroacetic acid dissociates partially in water according to the equilibrium below. What is the percentage of molecules dissociated in a 1.00 molal solution of trichloroacetic acid in water if the measured freezing point is -2.53C? The freezing point and Kf for water are 0.00C and 1.86 C-kg/mol, respectively. CCl3CO2H(aq) -> <- (Equalibrium arrows) CCl3CO2 1- (aq) + H+ (aq) How do I set up and Solve
A vessel contains a mixture of equimolar liquid benzene and liquid toluene that is in equilibrium...
A vessel contains a mixture of equimolar liquid benzene and liquid toluene that is in equilibrium with their vapors and air. The temperature of the mixture is 40 degrees celsius. The mole fraction of air in the vapor phase is .6 or 60%. What is the total pressure and the mole fraction of benzene in the vapor phase?
A mixture of benzene and toluene is in equilibrium with its vapor at 50oC. What mole...
A mixture of benzene and toluene is in equilibrium with its vapor at 50oC. What mole fraction of benzene is in the vapor phase? You may assume that this system follows Raoult's Law. Note: when solving Antoine's equation it is best to keep all sig figs through calculation and then truncate them at the end. Question options: 0.687, 0.807, 0.572, 0.614, 0.746, 0.913
A mixture of benzene and toluene is in equilibrium with its vapor at 50oC. What mole...
A mixture of benzene and toluene is in equilibrium with its vapor at 50oC. What mole fraction of benzene is in the vapor phase? You may assume that this system follows Raoult's Law. Note: when solving Antoine's equation it is best to keep all sig figs through calculation and then truncate them at the end.
A gas containing nitrogen, benzene, and toluene is in equilibrium with a liquid mixture of 30.0...
A gas containing nitrogen, benzene, and toluene is in equilibrium with a liquid mixture of 30.0 mole% benzene–70.0 mole% toluene at 50.0°C and 15.0 atm. Estimate the gas-phase composition (mole fractions using Raoult's law).
A solution of benzene and toluene is at equilibrium with vapour phase at 1 atm. Benzene...
A solution of benzene and toluene is at equilibrium with vapour phase at 1 atm. Benzene and toluene form ideal solution. The vapour phase, which is at equilibrium with liquid (solution) is ideal gas. Activity of benzene in solution is 0.3. a) Determine the temperature of the system at equilibrium. b) Determine the vapour pressure of benzene at the system’s temperature.
1. Vinegar consists of acetic acid, CH3COOH, and water. Write out the equilibrium expression for acetic...
1. Vinegar consists of acetic acid, CH3COOH, and water. Write out the equilibrium expression for acetic acid reacting with water. 2. Citric acid, H3C6H5O7, contributes to the acidity of many foods. Write out the equilibrium expression for citric acid reacting with water to lose one acidic proton.
Hydrocyanic acid will set up the following equilibrium when dissolved in water: HCN(aq) + H2O(l) <-->...
Hydrocyanic acid will set up the following equilibrium when dissolved in water: HCN(aq) + H2O(l) <--> CN-(aq) +H3O+(aq) a) calculate the pH of a .123 M solution of hydrocyanic acid ANSWER: pH = 5.01 b) To 500mL of the solution in part (a) is added 5.00g of solid NaCN. Calculate the pH of new solution. Assume no volume change has occured. c) If one were to add 10.00mL of a .100M NaOH solution to the solution prepared in part (b),...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT