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In: Chemistry

Structural data evolves with time, even for simple molecules. Consider the compounds E(CF3)3, i.e, the tris(trifluoromethyl)...

Structural data evolves with time, even for simple molecules. Consider the compounds E(CF3)3, i.e, the tris(trifluoromethyl) derivatives of P, As, and Sb. C-E-C bond angles were determined by gas-phase electron diffraction in the mid-20th century and given as: E=P, 99.6°; E=As, 100.1°; E=Sb, 100.0°.          

a) Does this trend seem reasonable, and explain your answer.                    

b) A more rigorous recent similar experiment gave a C-As-C bond angle of 95.4°, compared to a calculated value of 95.9°. In view of this which of the other two C-E-C bond angles seems most suspect, and why?

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