In: Chemistry
Notice that the elution time for each methyl ester increases by a factor of about 1.25...that is to say that the elution
time of methyl heptanoate (2.35min) can be predicted by looking at the elution time of the methyl ester that
preceeds it in the series-methyl hexanoate (1.87 min) and multiplying by 1.25 (1.87* 1.25 =2.33 or approx 2.35).
Similarly, the elution time for methyl octanoate (3.0 min) can be predicted my multiplying the elution time of methyl
heptanoate by 1.25...(2.35*1.25=2.9 or approx 3.0). Following this pattern, the predicted elution time of methyl
nonanoate is 3.75min (3.0* 1.25= 3.75), and the elution time of methyl decanoate is 4.7 min...(3.75* 1.25=4.68).
Therefore, the next ester in the homologous series is methyl decanoate