Question

In: Chemistry

Which of the following is an example of coupled reactions that are likely to be overall...

Which of the following is an example of coupled reactions that are likely to be overall spontaneous as written (select all that apply)? A + B -> C + D ΔG° = -10 kJ mol-1 / E + F -> C ΔG° = 2 kJ mol-1 A + B -> C + D ΔG° = 10 kJ mol-1 / D + E -> F ΔG° = -2 kJ mol-1 A + B -> C + D ΔG° = -10 kJ mol-1 / C + E -> F ΔG° = 2 kJ mol-1 A + B -> C + D ΔG° = -10 kJ mol-1 / A + 2 B -> E ΔG° = 2 kJ mol-1

Solutions

Expert Solution

answer : 1 , 3 ,4

1) A + B -> C + D ΔG° = -10 kJ mol-1 / E + F -> C ΔG° = 2 kJ mol-1 -------- spontaneous.

A + B -> C + D ΔG° = -10 kJ mol-1

E + F -> C        ΔG° = 2 kJ mol-1

____________________________

A + B + E + F -----------> 2 C + D , ΔG° = - 8 kJ mol-1

this is spontenous.

3) A + B -> C + D ΔG° = -10 kJ mol-1 / C + E -> F ΔG° = 2 kJ mol-1 ----------- spontaneous

A + B -> C + D ΔG° = -10 kJ mol-1

C + E -> F ΔG° = 2 kJ mol-1

_______________________________

A + B + E   ---------> D + F , ΔG° = - 8 kJ mol-1

this is spontenous.

4) A + B -> C + D ΔG° = -10 kJ mol-1 / A + 2 B -> E ΔG° = 2 kJ mol-1 ----------- spontaneous

A + B -> C + D ΔG° = -10 kJ mol-1

A + 2 B -> E ΔG° = 2 kJ mol-1

----___________________________

2 A + 3 B -------------> C + D + E , ΔG° = -8 kJ mol-1

this is spontanous.


Related Solutions

Which reactions of glycolysis are coupled to ATP hydrolysis? Which reactions involve substrate-level phosphorylation? Which reactions...
Which reactions of glycolysis are coupled to ATP hydrolysis? Which reactions involve substrate-level phosphorylation? Which reactions depend on either fermentation or aerobic respiration to continue?
Which of the following is a good example of a firm that is not likely to...
Which of the following is a good example of a firm that is not likely to be perfectly competitive? 19. 1) Farmer Joe's wheat. 2) Coyote Wile’s beef ranch. 3) Captain John's salmon farm. 4) Aviator Alan's nonstop airline service from Seattle to Nome. The demand curve faced by a competitive firm is 20. 1) perfectly elastic at the established market price. 2) downward sloping, with the same elasticity as the industry demand curve. 3) more inelastic than the demand...
The overall reactions and rate laws for several reactions are given below. Which one of these...
The overall reactions and rate laws for several reactions are given below. Which one of these represents an elementary step? A) A + 2B → P rate = k[A]2 B) A + 2B → P rate = k[A][B] c) 2A → P rate = k[A] D)A + B + C → P rate = k[A][C] E) A + B → P rate = k[A][B]
The following reactions can be coupled to give alanine and oxaloacetate: ?????????+???????? ⇋?????????????+??????? Δ??303°′=−1000 ?/??? ?????????+????????????...
The following reactions can be coupled to give alanine and oxaloacetate: ?????????+???????? ⇋?????????????+??????? Δ??303°′=−1000 ?/??? ?????????+???????????? ⇋?????????????+????????? Δ??303°′=−4810 ?/??? Write the equation for Keq and solve for the below combined reaction at 303.15 K: b)In the cytoplasm of a certain cell, reaction components were found to be at the following concentrations: pyruvate = 10-3 M, aspartate = 10-3 M, alanine = 10-4 M, oxaloacetate = 10-6 M.Calculate the Gibbs free energy change for the reaction in part (a) under these...
which of following is likely ti be an example of perfect competitive market
which of following is likely ti be an example of perfect competitive market
Coupled Reactions. Let us assume that 2 reactions are connected as stated below; A + Pi...
Coupled Reactions. Let us assume that 2 reactions are connected as stated below; A + Pi <------> BPi Keq at 37 C is 0.02 and S<----->C + Pi Keq at 37 C is 1000 a) Determine the Standard state energy value (ΔG0) for each reaction then determine the value for the coupled reaction. (hint – you know the Keq value – how would the related equation be set up?) b) Do you think this reaction would proceed spontaneously at STP...
The following reactions can be coupled to give alanine and oxaloacetate: glutamate + pyruvate ↔ ketoglutarate...
The following reactions can be coupled to give alanine and oxaloacetate: glutamate + pyruvate ↔ ketoglutarate + alanine ∆Go ’rxn,303 = − 1004 J/mol glutamate + oxaloacetate ↔ ketoglutarate + aspartate ∆Go ’rxn,303 = − 4812 J/mol (a) Write the form of the equilibrium constant for pyruvate + aspartate ↔ alanine + oxaloacetate and calculate the numerical value of the equilibrium constant at 30o C. (b) In the cytoplasm of a certain cell, the components are at the following concentrations:...
Which of the following reactions will not occur as written?Which of the following reactions will...
Which of the following reactions will not occur as written? Which of the following reactions will not occur as written? Zn (s) + Pb(NO3)2 (aq) → Pb (s) + Zn(NO3)2 (aq) Co (s) + 2AgCl (aq) → 2Ag (s) + CoCl2 (aq) Co (s) + 2HI (aq) → H2 (g) + CoI2 (aq) Sn (s) + 2AgNO3 (aq) → 2Ag (s) + Sn(NO3)2 (aq) Mg (s) + Ca(OH)2 (aq) → Ca (s) + Mg(OH)2 (aq)
Identify the likely corrosion mechanisms at the following locations: a. Hip stem made of titanium coupled...
Identify the likely corrosion mechanisms at the following locations: a. Hip stem made of titanium coupled with a cobalt chromium head b. Nitinol stent c. Fracture fixation plate made of stainless steel
Given the following reactions, what is the overall reaction and the ∆Hrxn 2A + B →...
Given the following reactions, what is the overall reaction and the ∆Hrxn 2A + B → A2B ∆H° = – 25.0 kJ/mol 2A2B → 2AB + A2 AB2  → Α + 2Β ∆H° = 35.0 kJ/mol ∆H° = – 15.0 kJ/mol A) A + A2B →  AB + A2 ∆Hrxn = +5 kJ/mol B) 2A + B + 2A2B + AB2  → A2B + 2AB + A2 + A + B ∆Hrxn = -5 kJ/mol C) A + A2B →  AB + A3 ∆Hrxn...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT