Question

In: Chemistry

What amount of energy, in kJ, is released when a mole of Co-57 undergoes electron capture?...

What amount of energy, in kJ, is released when a mole of Co-57 undergoes electron capture? Recall that 1 J = 1 kgm2/s2.

mass of nucleus Co-57: 56.93629 amu

mass of nucleus Fe-57: 56.93539 amu

mass of electron: 0.000549 amu

Solutions

Expert Solution

The reaction involved is

Co-57 + e- ---------> Fe-57

Energy = (mass defect)*velocity of light

Mass defect = Mass of Fe-57 - (Mass of Co-57 + mass of electron)

= 56.93539 amu - (56.93629 amu - 0.000549 amu)

= -0.001449 amu

In units of kg, 1 amu = 1.66054 x 10-27 kg

Mass defect = -0.001449 amu * 1.66054 x 10-27 kg/amu

= - 2.4061 x 10-30 kg

velocity of light = 2.9979 x 108 m/s

Energy = mass defect * (velocity)2

= (- 2.4061 x 10-30 kg)*( 2.9979 x 108 m/s)2

= -21.624 x 10-14 kgm2/s2

= -21.624 x 10-14 J/atom

So, amount of energy released by electron capture of 1 atom of Co-57 = 2.16 x 10-10 kJ

For 1 mole of Co-57, the energy released will be 2.16 x 10-10 kJ * 6.022 x 1023

= 1.30 x 1014 kJ (Answer)


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