Question

In: Chemistry

Calcium nitrate and ammonium fluoride react to form calcium fluoride, dinitrogen monoxide, and water vapor. What...

Calcium nitrate and ammonium fluoride react to form calcium fluoride, dinitrogen monoxide, and water vapor. What mass of each substance is present after 10.61 g of calcium nitrate and 11.06g of ammonium fluoride react completely?

Solutions

Expert Solution

Ca(NO3)2 (aq) + 2NH4F-----------> CaF2 + 2N2O + 4H2O

no of moles of Ca(NO3)2   = W/G.M.Wt   = 10.61/164   = 0.065moles

no of moles of NH4F        = W/G.M.Wt     = 11.06/37    = 0.298 moles

2 moles of NH4F react with 1 moles of Ca(NO3)2

0.298 moles of NH4F react with = 1*0.298/2   = 0.149 moles of Ca(NO3)2 is required

Ca(NO3)2 is limiting reactant

Ca(NO3)2 (aq) + 2NH4F-----------> CaF2     +          2N2O        +    4H2O

0.065 moles                                    0.065 moles      2*0.065 moles      4*0.065 moles

mass of CaF2 = no of moles * gram molar mass

                        = 0.065*78   = 5.07g

mass of N2O   = no of moles * gram molar mass

                       = 2*0.065*44   = 5.72g

mass of H2O = no of moles * gram molar mass

                       = 4*0.065*18   = 4.68g


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