Question

In: Chemistry

(a) when 1/2N2(g)+3/2H2(g)?NH3(g) for NH3(g) find the value of ?H?f. (b) when S(s)+O2(g)?SO2(g) For SO2(g) find...

(a) when 1/2N2(g)+3/2H2(g)?NH3(g)

for NH3(g) find the value of ?H?f.

(b) when S(s)+O2(g)?SO2(g)

For SO2(g) find the value of ?H?f.

(c) when Rb(s)+12Cl2(g)+32O2(g)?RbClO3(s)

For RbClO3(s) find the value of ?H?f.

Solutions

Expert Solution

The molar enthalpy of formation of a compound is the enthalpy change (heat) during the reaction of formation of 1 mole of the compound from its elements in their standard states (P=1 atm).

1 molecule of NH3 contains 1 N atom and 3 H atoms. The standard states of N and H are N2(g) and H2(g), respectively.

The molar enthalpy of formation of NH3 is the enthalpy change during the reaction of formation of 1 mole of NH3 from N2(g) and H2(g).

1 molecule of SO2 contains 1 sulfur atom and 2 oxygen atoms. The standard states of sulfur and oxygen are S(s) and O2(g), respectively.

The molar enthalpy of formation of SO2 is the enthalpy change during the reaction of formation of 1 mole of SO2 from S(s) and O2(g).

1 molecule of RbClO3 contains 1 Rb atom, 1 Cl and 3 O atoms. The standard states of Rb and Cl, and O are Rb(s), Cl2(g) and O2(g), respectively.

The molar enthalpy of formation of RbClO3 is the enthalpy change during the reaction of formation of 1 mole of RbClO3from Rb(s), Cl2(g) and O2(g).


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