In: Chemistry
Calculate Δ G ∘ rxn for the following reaction: 4CO(g)+2N O 2
(g)→4C O 2 (g)+ N 2 (g) . Use the following reactions and given Δ G
∘ rxn values: 2NO(g)+ O 2 (g)→2N O 2 (g) , Δ G ∘ rxn = - 72.6 kJ
2CO(g)+ O 2 (g)→2C O 2 (g) , Δ G ∘ rxn = - 514.4 kJ 1 2 O 2 (g)+ 1
2 N 2 (g)→NO(g) , Δ G ∘ rxn = 87.6 kJ Express your answer using one
decimal place. Δ G ∘ rxn = nothing kJ 2) Consider the following
reaction:
CO(g)+2H2(g)⇌CH3OH(g)
Kp=2.26×104 at 25 ∘C. Calculate ΔGrxn for the
reaction at 25 ∘C under each of the following conditions.
Part A
standard conditions
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ΔGrxn = | kJ |
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Part B
at equilibrium
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ΔGrxn = | kJ |
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Part C
PCH3OH= 1.1 atm ;
PCO=PH2= 1.5×10−2 atm
Express your answer using two significant figures.
3)
For the decomposition of barium carbonate, consider
the following thermodynamic data (Due to variations in
thermodynamic values for different sources, be sure to use the
given values in calculating your answer.):
Express your answer to four significant figures and include the appropriate units. View Available Hint(s) SubmitPrevious AnswersRequest Answer Relationship between free energy and the equilibrium constant The standard free energy change, ΔG∘ , and the equilibrium constant K for a reaction can be related by the following equation:ΔG∘=−RTlnK where T is the Kelvin temperature and R is equal to 8.314 J/(mol⋅K) .Part B Part complete The thermodynamic values from part A will be useful as you work through part B:
BaCO3(s)→BaO(s)+CO2(g)
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