Question

In: Chemistry

Which of the following species is least likely to function as a ligand in a transition-metal...

Which of the following species is least likely to function as a ligand in a transition-metal coordination compound?

a. BH3

b. CO32–

c. H2O

d. NF3

e. Cl

Solutions

Expert Solution

Ligand must be an electron-rich species for functioning as a ligand in a transition-metal coordination compound.

Lewis structure of given species are shown below.

s.no. Species Lewis structure electron rich or deficient
a BH3 deficient
b CO32– rich
c H2O rich
d NF3 rich
e Cl rich

From above structures it is clear that is least likely to function as a ligand in a transition-metal coordination compound because central atom of is electron-deficient  or only 6 electrons around boron (should 8 i.e. incomplete octet).

Therefore, option (a) is correct.


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