from an analysis of IR spectrum of dimedone , is it possible to
determine the keto/enol...
from an analysis of IR spectrum of dimedone , is it possible to
determine the keto/enol ratio? How can one do this ? Describe two
other methods to distinguish between the keto-and enol-forms in
organic chemistry.
Identify the compound A (C5H10O) with the proton NMR spectrum
shown. Compound A has IR absorptions at 3200–3600 cm–1 (strong,
broad), 1676 cm–1 (weak), and 965 cm–1, and also has 13C NMR
absorptions (attached protons in parentheses) at δ 17.5 (3), δ 23.3
(3), δ 68.8 (1), δ 125.5 (1), and δ 135.5 (1). Compound A may be
resolved into enantiomers; draw one molecule of A, omitting
wedge/dash bonds.
What peaks, if any, would be seen in the IR spectrum
if unreacted starting materials were present in the final product.
(Isopentyl alcohol reacts with acetic acid to produce isopentyl
acetate).
1.Which C = O aliphatic group absorbs more to the right of the
IR spectrum? Show an example and explain the reason.
2. What functional groups show characteristic absorptions in the
region of traces of the IR spectrum? Provide one molecule for each
case
3.What is the expression for the Planck equation as a function
of the wave number? Apply it to calculate the energy when is
equal to 3.0 μ. Emphasize the units
List three changes you would expect in the IR spectrum of
2,3-dibromocinnamic acid as compared to the IR spectrum of
trans-cinnamic acid. Make sure to reference the approximate
wavenumber of any relevant peaks and whether they correspond to a
stretch or a bend.
The IR spectrum of HCN shows 3 absorption bands at 3312 cm^-1,
2089 cm ^-1, and 712cm^-1. From this info alone can you deduce
whether HCN is linear or not? Explain.