In a 60 MHz spectrometer(corresponding to a magnetic field of 14,092 gause) the proton in CH3Cl...

In a 60 MHz spectrometer(corresponding to a magnetic field of 14,092 gause) the proton in CH3Cl absorb at a position 180 Hz down field from TMS.

(a) Determine chemical shift () of CH3 proton, also predict what would be the spectrum looks like if you use CD3Cl instead of Methyl chloride. (

b) Determine the difference in magnetic field required for resonance of CH3Cl proton compared to TMS (tri-methyl silane).(

c) What is the chemical shift of these protons in 300 MHz machine, and how many hertz downfield from TMS would they absorb at 300MHz? (H0 = 70,459 gauss)

Solutions

Expert Solution

queen_honey_blossom answered 1 year ago

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