Question

In: Chemistry

What is the concentration of Ca2+ in ppm (mg/L) in cave water saturated with calcite (calcium...

What is the concentration of Ca2+ in ppm (mg/L) in cave water saturated with calcite (calcium carbonate, Ksp = 4.7 × 10-9)?

Answer:2.7

Solutions

Expert Solution

Ksp   =   4.7 x 10^-9

CaCO3 ------------------------> Ca+2 + CO3-2

Ksp = [Ca+2][CO3-2]

4.7 x 10^-9 = S^2

S = 6.86 x 10^-5 M

molarity of Ca+2 = 6.86 x 10^-5 M

ppm   = mg / L

molarity of Ca+2 = 6.86 x 10^-5 mol / L

                          = ( 6.86 x 10^-5 mol / L ) x ( 40 g / mol )

                           = 2.7 x 10^-3 g / L

                            = 2.7 mg / L

                           = 2.7 ppm ------------------------> answer


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