Question

In: Chemistry

For the reaction shown, find the limiting reactant for each of the following initial amounts of...

For the reaction shown, find the limiting reactant for each of the following initial amounts of reactants.
2Li(s)+Cl2(g)→2LiCl(s)

(Please show typed out problem solving. I'm trying to get a grasp of how this works, and I have a hard time reading the hand-written answers,.) Thank you!

Part A

1.0 gLi; 1.0 gCl2

Express your answer as a chemical formula.

Part B

10.5 gLi; 37.2 gCl2

Express your answer as a chemical formula.

Part C

2.85×103gLi; 6.79×103gCl2

Express your answer as a chemical formula.

Solutions

Expert Solution

Let us write the equation once again

2 Li(s) + Cl2(g) ----------> 2 LiCl(s)

PART (A)

Weight of Li =1 gram

Weight of Cl2 = 1 gram

Molas mass of LI=6.94 g/mole

Molar mass of Cl2 = 35.5(2) = 71 g/ mole

Moles of Li =weight of Li/ Molar mass of Li

                = 1/6.94 = 0.144 moles

Moles of Cl2 = Weight of Cl2/ Molar mass of Cl2

                  = 1/71 = 0.01408 moles

Now per the reaction stiochometery

       2 mole of Licl = 1 moles of Cl2

   Therefore moles of Cl2 required for 0.144 moles of Li = (1/2) * 0.144 =0.072 moles

But number of moles of Cl2 available is only 0.01408 moles. Hence it will get completely used up

and Li will reamain in excess

Limiting reactang : Chlorine

Part (B)

Weight of Li =10.5 gram

Weight of Cl2 = 37.2 gram

Molas mass of LI=6.94 g/mole

Molar mass of Cl2 = 35.5(2) = 71 g/ mole

Moles of Li =weight of Li/ Molar mass of Li

                = 10.5/6.94 = 1.5129 moles

Moles of Cl2 = Weight of Cl2/ Molar mass of Cl2

                  = 37.2/71 = 0.524 moles

Now per the reaction stiochometery

       2 mole of Licl = 1 moles of Cl2

Moles of Cl2 required for 1.5129 moles of Li =(1/2)*1.5129 = 0.75645 moles

But moles of Cl2 available is only 0.524 moles. Hence it will get completely used up and Li will reamin in exces

Limiting reactang : Chlorine

Part (C)

Weight of Li =2.85*103 gram

Weight of Cl2 = 6.79*103 gram

Molas mass of LI=6.94 g/mole

Molar mass of Cl2 = 35.5(2) = 71 g/ mole

Moles of Li =weight of Li/ Molar mass of Li

                = 2.85*103/6.94 = 410.663 moles

Moles of Cl2 = Weight of Cl2/ Molar mass of Cl2

                  = 6.79*103/71 = 95.6338 moles

Now per the reaction stiochometery

       2 mole of Licl = 1 moles of Cl2

Moles of Cl2 required for 410.663 moles of Li =(1/2)*410.663 = 205.3315 moles

But moles of Cl2 available is only 95.6338 moles. Hence it will get completely used up and Li will reamin in exces

Limiting reactang : Chlorine


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