Question

In: Chemistry

Part A Calculate [OH−] for 1.20 mL of 0.220 M NaOH diluted to 1.50 L Part...

Part A Calculate [OH−] for 1.20 mL of 0.220 M NaOH diluted to 1.50 L

Part B.Calculate [OH−] for a solution formed by adding 4.60 mL of 0.120 M KOH to 14.0 mL of 8.1×10−2 M Ca(OH)2

Thank you!!

Solutions

Expert Solution

before dilution                                          After dilution

M1   = 0.22M                                              M2 =

V1   = 1.2ml                                                 V2 = 1.5L   = 1500ml

M1V1   = M2V2

M2      = M1V1/V2

            = 0.22*1.2/1500   = 0.000176M

POH   = -log[OH-]

             = -log0.000176

              = 3.7544

PH        = 14-POH

             = 14-3.7544

             = 10.2456

part-B

no of moles of KOH   = molarity * volume in L

                                   = 0.12*0.0046   = 0.000552 moles

no of moles of Ca(OH)2   = molarity * volume in L

                                         = 0.081*0.014    = 0.001134 moles

Ca(OH)2 -------------------> Ca^+2(aq) + 2OH^-

0.001134 moles                                       2*0.001134 moles

Total no of moles of OH^-   = 0.000552 + 2*0.001134   = 0.00282 moles

Total volume in L                = 0.0046 + 0.014     = 0.0186 L

molarity OH^-         = no of moles/volume in L

                                 = 0.00282/0.0186    = 0.1516M


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