In: Chemistry
In: Chemistry
In: Chemistry
A) A 193.0 L sample of gas of the upper atmosphere at a pressure of 4.8 torr is compressed into a 256.0 mL container at the same temperature. What is the new pressure?
B) To what volume would the original sample have had to be
compressed to reach a pressure of 7.0 atm?
In: Chemistry
In: Chemistry
one mole of ice at 0 C is turned completely into steam by heating under 1 atm pressure. calculate the entropy change in the system with specific heat capacity and enthalpy/heat values.assuming they are all constant.
In: Chemistry
Question: A reaction A + B <==> C has a standard free-...
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A reaction
A + B <==> C
has a standard free-energy change of -3.22 kj/mol at 25oC
What are the concentrations of A, B, and C at equilibrium if at the
beginning of the reaction their concentrations are 0.30M, 0.40M and
0M respectively?
How would your answers above change if the reaction had a standard
free-energy change of +4.88 kj/mol?
____ there would be no change to the answers.
____ All concentrations would be lower.
____ All concentrations would be higher.
____ There would be less A and B but more C.
____ There would be more A and B but less C.
In: Chemistry
[Problem 15-5, p.679 in Henry and Heinke.] Some of the important characteristics of each of the reactors at the Pickering Nuclear Generating Station are as follows:
Thermal output: 1744 MW
Number of fuel channels: 390
Fuel bundles per channel: 12
Uranium content per fuel bundle: 19.8 kg
Total weight of fuel bundle: 23.7 kg
Length of fuel bundle: 49.5 cm
Outside diameter of fuel bundle: 10.2 cm
Average burnup of fuel: 7500 MWd thermal/tonne U
Assume that each reactor achieves a capacity factor [CF] of 0.8, where CF = (Actual energy
produced) / (Perfect production). Calculate:
a) The number of new fuel bundles per reactor required for each day of operation.
b) The length of a rectangular container of cross-section, 2.6 m x 2.6 m, required to accommodate one year's output of spent fuel from each reactor. Assume that each bundle fits inside a rectangular box of outside dimensions 10.4 x 10.4 x 50 cm.
In: Chemistry
Problem 5.1
Consider the formation of glucose from carbon dioxide and water
(i.e., the reaction of the photosynthetic process):
6CO2(g)+6H2O(l)?C6H12O6(s)+6O2(g).
The following table of information will be useful in working this
problem:
T= 298 K | CO2(g) | H2O(l) | C6H12O6(s) | O2(g) |
?H?f (kJ mol?1) | -393.5 | -285.8 | -1273.1 | 0.0 |
S? (J mol?1 K?1) | 213.8 | 70.0 | 209.2 | 205.2 |
C?P,m (J mol?1 K?1) | 37.1 | 75.3 | 219.2 | 29.4 |
Part A
Calculate the entropy change for this chemical system at 313 K .
Express your answer to four significant figures and include the appropriate units.
Part B
Calculate the enthalpy change for this chemical system at 313 K .
Express your answer to four significant figures and include the appropriate units.
Part C
Calculate the entropy change of the surroundings at 313 K .
Express your answer to three significant figures and include the appropriate units.
Part D
Calculate the entropy change of the universe at 313 K .
Express your answer to three significant figures and include the appropriate units.
In: Chemistry
Aluminum (FCC) with atom radius of 0.1431nm.
Find the distance between aluminum lattice plane (100) and (111), and calculate the density of that planes.
In: Chemistry
12. A 15.7-g sample of sodium carbonate is
added to a solution of acetic acid weighing 19.4
g. The two substances react, releasing carbon dioxide gas to the
atmosphere. After reaction, the contents of the reaction vessel
weighs 28.4 g.
What is the mass of carbon dioxide given off during the
reaction?
13. Cadmium metal reacts vigorously with yellow crystals of sulfur to produce a yellow powder of cadmium sulfide. A chemist determines that 112 g of cadmium reacts with 32.1 g of sulfur. How much cadmium sulfide could be produced from 45.4 g of cadmium metal?
18. Pick if it is a chemical or physcial reaction
(a) Pure water is obtained from ocean water by evaporating the water, then condensing it. |
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(b) Mercury is obtained by heating the substance mercury(II) oxide; oxygen is also obtained. |
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(c) Zinc is produced through the electrolysis of aqueous zinc sulfate |
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(d) Gold is obtained from river sand by panning (allowing the heavy metal to settle in flowing water). |
In: Chemistry
Recycling one aluminum can save enough energy to charge the average smartphone for 14 hours?
Recycling one aluminum can save enough energy to charge a TV for 3 hours?
Recycling one aluminum can give an indicudualy roughly the energy to recycle 19 more aluminum cans?
Can someone please show the calculations for these energy equivalents? Thank you!
In: Chemistry
Be sure to answer all parts.
Calculate the pH during the titration of 40.00 mL of 0.1000
M HCl with 0.1000 M NaOH solution after the
following additions of base:
(a) 20.00 mL
pH =
(b) 39.40 mL
pH =
(c) 52.00 mL
pH =
In: Chemistry
Calculate the pH of a 25 mg/L solution of hydrofluroic acid.
HF = H+ + F- Ka=10^-3.2
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ALL WITH EXPLANATIONS please :)
12. Consider the following reaction: 2SO2(g) + O2(g) ⇄ 2SO3(g) +E
Which of the following will not shift the equilibrium to the right?
A. Adding more O2
B. Adding a catalyst
C. Increasing the pressure
D. Lowing the temperature
13. Consider the following equilibrium system: CaCO3(s) ⇄ CaO(s) + CO2(g)
Which one of the following changes would cause the above system to shift left?
A. Add more CaO
B. Remove CaCO3
C. Increase pressure
D. Remove CO2
14. Consider the following equilibrium: SO2Cl2(g) + energy ⇄ SO2(g) + Cl2(g)
When the temperature is decreased, the equilibrium shifts
A. Left and [ SO2Cl2 ] increases
B. Left and [ SO2Cl2 ] decreases
C. Right and [ SO2Cl2 ] increases
D. Right and [ SO2Cl2 ] increases
15. Consider the following equilibrium system: CO2(g) + H2(g) ⇄ CO(g) + H2O(g)
Which of the following, when added to the system above, would result in a net decrease in [H2O]?
A. CO2
B. H2
C. CO
D. H2
16. Consider the following equilibrium: C(s) + 2H2(g) ⇄ CH4(g) + 74 kJ
When a small amount of solid C is added to the system
A. [H2] decreases
B. [CH4] increases
C. The temperature increases
D. All concentrations remain constant
17. Consider the following equilibrium: 2NO(g) + Cl2(g) ⇄ 2NOCl(g)
At constant temperature and volume, Cl2 is added to the above equilibrium system. As equilibrium re-establishes, the
A. [NOCl] will decrease
B. The temperature increases
C. [NO] will increase
D. [NOCl] will increase
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