How many nitrate ions are present in 150.0 mL of 0.0875 M iron(III)nitrate?
How would you prepare 2.50 L of 0.0683 M CaCl2 from a 0.388 M
solution of CaCl2?
In: Chemistry
This is from wittig reaction experiment-organic chemistry
In: Chemistry
A wastewater containing 150 mg/l chlorobenzene is treated in a laboratory adsorption unit using a PVC column, 1.0 inch internal diameter, to an effluent concentration of 15 mg/l . Service times, and throughput volumes at specified depths and flowrates associated with a breakthrough concentration of 15.0 mg/l are given in table 1.
table1 : result of adsorption column experiment
Loading rate,gpm/ft2 Bed depth,ft Throughput volume, gal Time, hr
|
loading rate gpm/ft2 |
bed depth ft |
throughput volume, gal |
time, hr |
| 2.5 | 3.0 | 810 | 980 |
| 5.0 | 1750 | 2230 | |
| 7.0 | 2910 | 3440 | |
| 5.0 | 3.0 | 605 | 420 |
| 5.0 | 1495 | 1000 | |
| 9.0 | 3180 | 2185 | |
| 7.5 | 5.0 | 1183 | 452 |
| 9.0 | 2781 | 1075 | |
| 12.0 | 4000 | 1564 |
1) is the attainable effluent concentration satisfactory from a regulatory standpoint?
2) determine the Bohart-Adams constant ( K,N0 and x0) for each hydraulic loading.
3)base on data derived above design an adsorption column 2.0 ft internal diameter to treat a wastewater flow 5,000 gal/d containing 150 mg/l of CB. The attainable effluent concentration is 15 mg/l and it is desired to operate the column for 90 days(8 hourslday,7 days/week) before reching exhaustion.
4)calculate the yearly carbon requirements in cubic feet.
what kind of information do you need? these are all what i got from paper
In: Chemistry
Define and differentiate between the terms reaction rate, rate expression, rate law, reaction order, and instantaneous rate law.
In: Chemistry
4Au(s) + 16KCN(aq) + 3O2(g) + 6H2O(l) --> 4KAu(CN)4(aq) + 12KOH(aq) Balance using half reaction method. show all steps
In: Chemistry
a) Write a balanced reaction for the formation of a polysiloxane starting form (CH3)2SiCl2
b) Liquid silcones (polysiloxanes) are used of a variety of applications what are they and why are silicones used over hydrocarbon oils?
In: Chemistry
Cl=8 F=22
(a) How many chlorine trifluoride molecules are formed in the reaction depicted above?
(b) How many chlorine molecules remain after the reaction has gone to completion?
(c) How many fluoride molecules remain after the reaction has gone to completion?
(d) Which is the limiting reactant in the reaction depicted above?
(e) If the reaction was carried out with 2.05 moles of chlorine gas and 4.46 moles of fluorine gas, how many moles of chlorine trifluoride would be produced?
(f) If the reaction was carried out with 2.05 g of chlorine gas and 4.46 g of fluorine gas, how many grams of chlorine trifluoride would be produced?
In: Chemistry
Titration of 50.0mL of 0.100M HX (Ka=1.5x10^-5) with 0.100M NaOH. Calculate the pH of:
- buffer formed at the addition of 12.5mL NaOH
- buffer formed at the addition of 25.0mL NaOH
- buffer formed at the addition of 37.5mL NaOH
- solution obtained at the endpoint
Please do the endpoint especially!
In: Chemistry
Sulfur hexafluoride and Sulfur tetrafluoride are two common halides of sulfur.
a) Draw their lewis dot structures and describe their molecular shapes including bond angles.
b) Write a balanced reaction for the synthesis of SF6.
c) Describe in detail the differences in reactivity and chemistry of the observed by the two compounds.
d) Please describe in as much detail as possible, uses for SF6.
In: Chemistry
A) A buffer solution contains 0.484 M
KHCO3 and
0.314 M
K2CO3.
Determine the pH change when
0.126 mol NaOH is added to
1.00 L of the buffer.
pH after addition − pH before addition = pH change
=
B) A buffer solution contains 0.335 M
NH4Br and
0.313 M NH3
(ammonia). Determine the pH
change when 0.072 mol
KOH is added to 1.00 L of the
buffer.
pH after addition − pH before addition = pH change
=
C) Determine the pH change when
0.086 mol HI is added to
1.00 L of a buffer solution that is
0.442 M in CH3COOH and
0.368 M in
CH3COO-.
pH after addition − pH before addition = pH change
=
In: Chemistry
A) Consider how best to prepare one liter of a buffer solution with pH = 4.94 using one of the weak acid/conjugate base systems shown here.
| Weak Acid | Conjugate Base | Ka | pKa |
|---|---|---|---|
|
HC2O4- |
C2O42- |
6.4 x 10-5 |
4.19 |
|
H2PO4- |
HPO42- |
6.2 x 10-8 |
7.21 |
|
HCO3- |
CO32- |
4.8 x 10-11 |
10.32 |
How many grams of the potassium salt of the weak
acid must be combined with how many grams of the
potassium salt of its conjugate base, to produce
1.00 L of a buffer that is 1.00 M
in the weak base?
grams potassium salt of weak acid =
grams potassium salt of conjugate base =
B) Design a buffer that has a pH of 3.75 using one of the weak acid/conjugate base systems shown below.
| Weak Acid | Conjugate Base | Ka | pKa |
|---|---|---|---|
|
HC2O4- |
C2O42- |
6.4×10-5 |
4.19 |
|
H2PO4- |
HPO42- |
6.2×10-8 |
7.21 |
|
HCO3- |
CO32- |
4.8×10-11 |
10.32 |
How many grams of the sodium salt of the weak acid
must be combined with how many grams of the sodium
salt of its conjugate base, to produce 1.00 L of a
buffer that is 1.00 M in the weak base?
grams sodium salt of weak acid
= g
grams sodium salt of conjugate base
= g
C) Consider how to prepare a buffer solution with pH = 9.52 (using one of the weak acid/conjugate base systems shown here) by combining 1.00 L of a 0.301-M solution of weak acid with 0.365 M potassium hydroxide.
| Weak Acid | Conjugate Base | Ka | pKa |
|---|---|---|---|
|
HNO2 |
NO2- |
4.5 x 10-4 |
3.35 |
|
HClO |
ClO- |
3.5 x 10-8 |
7.46 |
|
HCN |
CN- |
4.0 x 10-10 |
9.40 |
How many L of the potassium hydroxide solution
would have to be added to the acid solution of your
choice?
Design a buffer that has a pH of 7.29 using one
of the weak base/conjugate acid systems shown below.
| Weak Base | Kb | Conjugate Acid | Ka | pKa |
|---|---|---|---|---|
|
CH3NH2 |
4.2×10-4 |
CH3NH3+ |
2.4×10-11 |
10.62 |
|
C6H15O3N |
5.9×10-7 |
C6H15O3NH+ |
1.7×10-8 |
7.77 |
|
C5H5N |
1.5×10-9 |
C5H5NH+ |
6.7×10-6 |
5.17 |
D) How many grams of the chloride salt of the
conjugate acid must be combined with how many grams of the weak
base, to produce 1.00 L of a buffer that is
1.00 M in the weak base?
grams chloride salt of conjugate acid =
grams weak base =
In: Chemistry
Calculate the pH of a 0.01 M solution of sodium benzoate.
A: Dissociation constant of benzoic acid.
B: Calculate the hydrolysis constant of sodium benzoate.
C: Calculate the pH of the 0.01 M solution.
In: Chemistry
Explain what is olefin metathesis? in one paragraph
In: Chemistry
The reaction of nitrogen gas with hydloric acid is as follows:
N2 (g) + 6 HCl (g)
In: Chemistry
please calculate the
1.theoretical yield,
2.percent yield, and
3. overall percent yield from benzaldehyde.
my products weight was 2.137 g
experiment was "Isolation of Tetraphenylcyclopentadienone, then Recrystalization of Tetraphenylcyclopentadienone"
HERE IS MY PROTOCOL I FOLLOWED TO GET MASS OF 2.137 g
THIS IS ALL AVAILABLE INFORMATION!!!
Add 1.5 g benzil, 1.5 g dibenzyl ketone, and 12 mL absolute ethanol to a 50-mL round-bottom flask. Place a magnetic stir bar in the flask. Attach a condenser, having lightly greased the joint. Stir and heat the mixture at 70ºC (with the condenser running) until the solids dissolve. Then raise the temperature to 80ºC with continued stirring. Using a 9" Pasteur pipette, add dropwise 2.25 mL of ethanolic potassium hydroxide solution through the condenser into the flask; make an effort to prevent any drops from contacting the condenser walls (each drop should fall directly into the reaction mixture). The mixture will immediately turn a dark purple. Once you have added the potassium hydroxide, raise the temperature to about 85ºC. Stir the mixture at this temperature for 15 minutes.
Isolation of Tetraphenylcyclopentadienone
At the end of the heating period, remove the flask from the heat and allow it to cool to room temperature. Then place the flask in an ice-water bath for 5 minutes to complete the crystallization of the product. Collect the deep purple crystals on a Büchner funnel by vacuum filtration. Wash the crystals with 3 4-mL portions of ice-cold 95% ethanol; this wash solvent should be used to transfer crystals from the round-bottom flask to the Büchner funnel if they do not all come out when the mixture is initially poured into the funnel. After air-drying the crystals for a few minutes, complete the drying in a 100ºC-oven for a few minutes.
Recrystallizing Tetraphenylcyclopentadienone
Recrystallize your tetraphenylcyclopentadienone from a 1:1 mixture of 95% ethanol and toluene; approximately 24 mL of this solvent mixture will be required per gram of tetraphenylcyclopentadienone, but remember to only add the minimum boiling solvent necessary to dissolve the solute. Recover the crystals by vacuum filtration (as above) and redetermine the melting point.
Weigh the dried product and calculate the percent yield. Also calculate the overall percent yield from benzaldehyde. Determine the melting point. If the melting point is not within 2ºC of the literature value, you should recrystallize your product (see below).
In: Chemistry