In: Chemistry
(a) Derive a general expression for the energy difference between any two neighboring rotational state (i.e, the difference in energy between the L abd L+L states). (b) How does the energy difference change as L increases? (c) How does the energy difference change if the radius, r, of the rotating particle increases?
a) The energy difference between any two neighbouring rotational states can be derived using Law of conservation of energy, which in this case is written as Mechanical energy = Rotational Kinetic energy+ Potential energy ± forces between two particles (which can be attractive or repulsive)
m1 & m2 are masses of particles rotating in states L and L+L respectively, 'r' is the radius between the two rotating particles which in turn depends upon their postions.
ω1& ω2 are angular velocities
Writing energy equation for L state,
E1= 1/2(Σmiri2)Lω12 + m1g(0) ± Gm1m2/r2
( Σmiri2can also be written as I(inertia of motion), as it is the sum of individual kinetic energies of each of the sub-particles on a particle)
Similarly we can write energy equation for L+L State,
E2=1/2(Σmiri2)L+Lω22 + m2g(L) ± Gm1m2/r2 ( distance between 2 states as ' L')
therefore difference between two energy states will be,
E2 -E1= [1/2(Σmiri2)Lω12 + m1g(0) ± Gm1m2/r2 ] - [1/2(Σmiri2)L+Lω22 + m2g(L) ± Gm1m2/r2 ]
So, the final equation would be
ΔE = E2 -E1= 1/2 { (Σmiri2)Lω12 - (Σmiri2)L+L ω22 } + m2g(L) ± 2Gm1m2/r2 .
(b) from the above equation it is clear that ΔE is directly proportional to the L (ΔE∝ m2g(L) ), therefore the energy difference increases as L increases.
(c) This can also be known from the derived final expression, as ΔE ∝ GGm1m2/r2 (ΔE ∝1/r2, inversely proportional ), hence the energy difference decreases gradually as radius 'r' of the the rotating particle increases.