Question

In: Chemistry

(a) Derive a general expression for the energy difference between any two neighboring rotational state (i.e,...

(a) Derive a general expression for the energy difference between any two neighboring rotational state (i.e, the difference in energy between the L abd L+L states). (b) How does the energy difference change as L increases? (c) How does the energy difference change if the radius, r, of the rotating particle increases?

Solutions

Expert Solution

a) The energy difference between any two neighbouring rotational states can be derived using Law of conservation of energy, which in this case is written as Mechanical energy = Rotational Kinetic energy+ Potential energy ± forces between two particles (which can be attractive or repulsive)

m1 & m2 are masses of particles rotating in states L and L+L respectively, 'r' is the radius between the two rotating particles which in turn depends upon their postions.

ω1& ω2 are angular velocities

Writing energy equation for L state,

E1= 1/2(Σmiri2)Lω12 + m1g(0) ± Gm1m2/r2   

( Σmiri2can also be written as I(inertia of motion), as it is the sum of individual kinetic energies of each of the sub-particles on a particle)

Similarly we can write energy equation for L+L State,

E2=1/2(Σmiri2)L+Lω22 + m2g(L) ± Gm1m2/r2   ( distance between 2 states as ' L')

therefore difference between two energy states will be,

E2 -E1= [1/2(Σmiri2)Lω12 + m1g(0) ± Gm1m2/r2 ] - [1/2(Σmiri2)L+Lω22 + m2g(L) ± Gm1m2/r2 ]

So, the final equation would be

ΔE = E2 -E1= 1/2 { (Σmiri2)Lω12 - (Σmiri2)L+L ω22 } + m2g(L) ± 2Gm1m2/r2 .

(b) from the above equation it is clear that ΔE is directly proportional to the L (ΔE∝  m2g(L) ), therefore the energy difference increases as L increases.

(c) This can also be known from the derived final expression, as  ΔE ∝ GGm1m2/r2 (ΔE ∝1/r2, inversely proportional ), hence the energy difference decreases gradually as radius 'r' of the the rotating particle increases.


Related Solutions

Derive a general expression for the spacing between adjacent energy levels in the 2D Rigid Rotor.
Derive a general expression for the spacing between adjacent energy levels in the 2D Rigid Rotor.
Derive a general expression for the average failure rate of a Weibull distribution between two point...
Derive a general expression for the average failure rate of a Weibull distribution between two point in time, t1 and t2.
a. In general is there any difference between R and S, and + and -? between...
a. In general is there any difference between R and S, and + and -? between d- and l-, and + and -? b. Discuss the validity of the following statements: 1. A mixture of (+)- and (--)-carvone can be separated by column chromatography on silica gel using hexanes-acetone as elution. 2. In general, column chromatography on silica gel is run with a series of solvents of increasing polarity. 3. Carvone is more polar than limonene. c. Which compound, limonene...
a. In general is there any difference between R and S, and + and -? between...
a. In general is there any difference between R and S, and + and -? between d- and l-, and + and -? b. Discuss the validity of the following statements:         1. A mixture of (+)- and (--)-carvone can be separated by column chromatography on silica gel using hexanes-acetone as elution.         2. In general, column chromatography on silica gel is run with a series of solvents of increasing polarity.         3. Carvone is more polar than limonene. c....
What is the difference between a rotational vibrational Spectrum and pure rotational spectrum?
What is the difference between a rotational vibrational Spectrum and pure rotational spectrum?
a. State the ampere circuital law b. Derive expression for inductance of a Toroid? c. Derive...
a. State the ampere circuital law b. Derive expression for inductance of a Toroid? c. Derive the set of Maxwell’s equations with solutions in the integral form from the fundamental laws of a good conductor? d. Derive the expression for torque developed in a rectangular closed circuit current (I) in a uniform field?
.Derive the expression for energy and force in a double excited magnetic field              system
.Derive the expression for energy and force in a double excited magnetic field              system
What is the difference between work function and electron affinity energy? Is there any relation between...
What is the difference between work function and electron affinity energy? Is there any relation between work function and electron affinity energy?
By writing Bohr postulates, derive the expression of energy levels of the Hydrogen atom according to...
By writing Bohr postulates, derive the expression of energy levels of the Hydrogen atom according to the Bohr atom model.
Derive an expression for the most probable translational energy for an ideal gas. Compare your results...
Derive an expression for the most probable translational energy for an ideal gas. Compare your results to the mean translational energy for the same gas.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT