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In: Chemistry

Determine the Kanfor a .035 M weak (monoprotic) acid with a ph of 3.5. Show work...

Determine the Kanfor a .035 M weak (monoprotic) acid with a ph of 3.5. Show work too please?

Solutions

Expert Solution

weak monoprotic acid HA only weakly dissociates that means at equilibrium so of it is in the form HA and some of it is H+ and A-

HA dissociates into H+ and A-

HA <=======> H+ + A-

Ka is acid dissociation constant

lets do an ice chart to establish how much of each species is present at equilibrium

X amount of HA dissociates and X amount of H+ and X amount of A- is produced.

------ HA <======> H+ + A-
initial -- .060 ---------- 0 ---- 0
change - -X ---------- +X ---- +X
final ---- .035 - X ---- X ----- X

Ka = Products^coefficient/Reactants^coefficie...

Ka = [H+][A-]/[HA]

let's plug in our values at equilibrium into the equation

Ka = [X][X]/[.035-X]

Since .035 is much >>>>> bigger than X we can ignore X in the denominator

Ka = [X]^2/.035

[X] = H+ concentration

the pH can be used to calculate the H+ con

the pH can be used to calculate the H+ concentration

pH = -log [H+]

[H+] = 10^-3.5 = X =3.625*10-6

Plug in these values and you will get Ka. Hope it makes sense

ka= 3.625*10-6 *3.625*10-6 /0.035   = 375.46*10-12   = 3.75*10-10


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