In: Chemistry
10.33 predict the shape or geometry of the following mol-ecules , using theVSEPR model
A). SiF4
B). SF2
C) CoF2
D) PCl3
Answer ) A) TETRAHEDRAL
B) BENT
C) TRIGONAL PLANAR
D) TRIGONAL PYRAMIDAL
Explanation
Step 1 : draw the electron dot structure
Step 2 : arrange all the groups around central central atom to minimise repulsion
Step3 : count the number of line pairs and the number of atoms bonded to Central metal atom.
Step 4 : use vsepr to predict geometry .
A) SiF4
Atoms bonded to central atom: 4
Lone pair electrons of central atom: 0 pairs
Shape of SiF4 : TETRAHEDRAL because all 4 are bond pairs
B) SF2
Atoms bonded to central atom: 2
Lone pair electrons of central atom: 2 pairs (4 electrons total)
Shape of SF2 : BENT because there are 2 lone pairs which makes the whole structure distorted into bent shape
C)COF2
Atoms bonded to central atom : 3
Lone pair electrons of central atom : 0
Shape of COF2 : TRIGONAL PLANAR
D)PCl3
Atoms bonded to central atom: 3
Lone pair electrons of central atom : 1
Shape of PCl3: TRIGONAL PYRAMIDAL due to lone pair present