Question

In: Chemistry

The hydroxide ion has the formula OH−. The solubility-product constants for three generic hydroxides are given...

The hydroxide ion has the formula OH−. The solubility-product constants for three generic hydroxides are given here.

Generic hydroxide Ksp
XOH 1.70×10−8
Y(OH)2 2.70×10−10
Z(OH)3 8.30×10−15

The removal of an ion is sometimes considered to be complete when its concentration drops to 1.00×10−6  M. What concentration of hydroxide would cause Y2+ to "completely" precipitate from a solution?

Solutions

Expert Solution

concentration of hydroxide = 0.0164 M

Explanation

Ksp Y(OH)2 = 2.70 x 10-10

For complete precipitation of Y(OH)2, concentration of Y2+ = [Y2+] = 1.00 x 10-6 M

Ksp Y(OH)2 = [Y2+][OH-]2

2.70 x 10-10 = (1.00 x 10-6 M) * [OH-]2

[OH-]2 = (2.70 x 10-10) / (1.00 x 10-6 M)

[OH-]2 = 2.70 x 10-4

[OH-] = (2.70 x 10-4)1/2

[OH-] = 0.0164 M


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