In: Chemistry
i have data, Acid is HCl and base is NaOH
△H=mCh2o(Ti-Tf)
i am looking for the mass(m) please explain this..
Vacid |
Vbase |
Cacid |
Cbase |
Ti |
Tf |
50 mL |
50 mL |
1.0 M |
1.0 M |
22.4 C |
30.4 C |
Solution:
Volume in mL amd Concentration in M is given in the data, so mass can be calculated by using Molarity formulae,
Molarity = Moles / Volume in Litres { Moles = Mass / Molecular. weight}
Molecular weight of HCl = 36.5 and NaOH = 40
Mass of HCl is calculated by,
1.0 M = (Mass / 36.5) / 0.05
i.e., Mass of HCl = (1.0 *36.5) * 0.05 = 1.825 gram
Similarly for mass of NaOH is calculated by,
1.0 M = (Mass / 40) / 0.05
i.e., Mass of NaOH = (1.0*40) *0.05 = 2 grams
While calculating del H the mass of both HCl and NaOH have to be added to (1.825 + 2 = 3.825 gm) as both reactant combines to form product, so the m term in equation is m = 3.825 gm and Cwater = 4.186 @ STP, Tf = 30.4 C, Ti = 22.4 C
By substituting all the calculated values in equation gives,
Note : I took C value of water in J/gm C as the required is not mentioned in question the solution is given in standard unit.