Question

In: Chemistry

a) You have to prepare a pH 5.25 buffer from the following 0.100 M solutions available:...

a) You have to prepare a pH 5.25 buffer from the following 0.100 M solutions available:

1. hydrocyanic acid

2. hypobromous acid

3. propanoic acid

4. potassium cyanide

5. potassium hypobromite

6. potassium propanoate

Which solutions would you choose to make the most effective buffer? Why?

b) How many milliliters of each of each o the solutions selected in part a would you use to make one liter of the final buffer solution?

Solutions

Expert Solution

a.)

Propanoic acid - Ka = 1.3 x 105   

Of the acids listed, the Ka value for propanoic acid to potassium propanoate is closest to the desired hydrogen ion concentration. Therefore, you need only to adjust the ratio of [HC3H5O2]/[HC3H4O2-] to get the desired final hydrogen ion concentration. You can do this using the Henderson-Hasselbalch equation:

So, 3 and 6 should be used.

Required buffer,

pH = 5.25

H+ = 5.6 X 10-6

pH = pKa + log [acid]/[base]

H+ = Ka([HC3H5O2]/[HC3H4O2-])

5.6 X 10-6 = 1.3 x 10–5   ([HC3H5O2]/[HC3H4O2-])

([HC3H5O2]/[HC3H4O2-]) = 5.6/13 = 0.43/1

To satisfy the expression, the ratio of [HC3H5O2]/[HC3H4O2-] must be 0.43 to 1. Therefore, if you add 0.43 mol propanoic acid acid and 1.0 mol ptassium propanoate (or any other pair of amounts such that the ratio is still 2.8 to 1) to enough water to make 1.0 L of solution, the solution will be a buffer with a pH of 5.25.

So,, we have to use 4.3 L of 3.propanoic acid and 10 L of potassium propanoate to obtain buffer of pH =5.25.


Related Solutions

You have to prepare a ph 3.50 buffer, and you have the following 0.10M solutions available:...
You have to prepare a ph 3.50 buffer, and you have the following 0.10M solutions available: HCOOH, CH3COOH,H3PO4,HCOONa, CH3COONa, and NAH2PO4. Which solutions would you use? How many milliliters of each solution would you use to make approximately a liter of the buffer? The answer on the textbook is 360mL of 0.10M HCOONa and 630mL of 0.10M HCOOH. I just need to know how did they get that answer.
You have the following solutions at your disposal to prepare a buffer solution with a pH...
You have the following solutions at your disposal to prepare a buffer solution with a pH greater than 7.0: (1) 50.0 mL of 0.35 M NH3 Kb = 1.8×10-5  (2) 55.0 mL of 0.35 M NaOH (3) 50.0 mL of 0.35 M HCl (4) 16.5 mL of 0.35 M NaCl NaOH (5) 16.5 mL of 0.35 M HNO3 (6) 16.5 mL of 0.35 M KOH (a) Assuming that you are going to mix the entire quantity of the listed solutions to...
You need to prepare 100.0 mL of a pH = 4.00 buffer solution using 0.100 M...
You need to prepare 100.0 mL of a pH = 4.00 buffer solution using 0.100 M benzoic acid (pKa = 4.20) and 0.200 M sodium benzoate. How much of each solution should be mixed to prepare this buffer?
If you have 120. mL of a 0.100 M HEPES buffer at pH 7.55 and you...
If you have 120. mL of a 0.100 M HEPES buffer at pH 7.55 and you add 2.00 mL of 1.00 M HCl, what will be the new pH? (The pKa of HEPES is 7.55.) pH =
How can you prepare 100.0 mL of acetic buffer solution (0.100 M) with pH = 5.10...
How can you prepare 100.0 mL of acetic buffer solution (0.100 M) with pH = 5.10 by using a solution of acetic acid (25% w/w, density = 1.05 g/cm3 ) and pure sodium acetate. (pKa = 4.76; M. W. = 60.05 g/mol for HAc and 82.03 for NaAc).
You need to prepare 100.0 mL of a pH=4.00 buffer solution using 0.100 M benzoic acid...
You need to prepare 100.0 mL of a pH=4.00 buffer solution using 0.100 M benzoic acid (pKa = 4.20) and 0.120 M sodium benzoate. How much of this solution should be mixed to prepare this buffer? Sum of volumes must equal 100mL. Please explain clearly and show work! Thank you :)
You need to prepare 100.0 mL of a pH=4.00 buffer solution using 0.100 M benzoic acid...
You need to prepare 100.0 mL of a pH=4.00 buffer solution using 0.100 M benzoic acid (pKa = 4.20) and 0.220 M sodium benzoate. How much of each solution should be mixed to prepare this buffer? a) mL of benzoic acid b) mL of sodium benzoate
1. Calculate the pH of the following solutions. a. A solution containing 0.100 M KH2PO4 and...
1. Calculate the pH of the following solutions. a. A solution containing 0.100 M KH2PO4 and 0.200 M K2HPO4 b. A solution prepared by mixing 100.0 mL 0.100 M H3PO4 with 50.0 mL 0.150 M K3PO4 c. A solution prepared by mixing 100.0 mL of 0.100 M H3PO4 and 80.0 mL of 0.200 M KOH.
Determine the pH of each of the following two-component solutions. 0.270 M NH4NO3 and 0.100 M...
Determine the pH of each of the following two-component solutions. 0.270 M NH4NO3 and 0.100 M HCN 8.0×10−2 M RbOH and 0.120 M NaHCO3 8.2×10−2 M HClO4 and 2.2×10−2 M KOH 0.110 M NaClO and 5.50×10−2 M KI
Part A Calculate the pH of 0.100 L of a buffer solution that is 0.27 M...
Part A Calculate the pH of 0.100 L of a buffer solution that is 0.27 M in HF and 0.47 M in NaF. Express your answer using three significant figures. pH = SubmitMy AnswersGive Up Part B Calculate pH of the solution on addition of the following. 0.004 mol of HNO3 Express your answer using three significant figures. pH = SubmitMy AnswersGive Up Part C Calculate pH of the solution on addition of the following. 0.005 mol of KOH Express...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT