In: Chemistry
Calculate the amount of energy in kilojoules needed to change 333 g of water ice at −10 ∘C to steam at 125 ∘C. The following constants may be useful:
Cm (ice)=36.57 J/(mol⋅∘C)
Cm (water)=75.40 J/(mol⋅∘C)
Cm (steam)=36.04 J/(mol⋅∘C)
ΔHfus=+6.01 kJ/mol
ΔHvap=+40.67 kJ/mol
Solution :
Mass of water = 333 g
Moles of water(m) = 333 / 18 = 18.5 mol H2O
We have to solve this question step by step ;
Q1 = Amount of heat required to convert from ice at -10 oC to ice at 0 oC = mCm(ice)T1
Q1 = Amount of heat required to convert from ice at 0 oC to water at 0 oC = mHfus
Q2 = Amount of heat required to convert from water at 0 oC to water at 100 oC = mCm(water)T2
Q3 = Amount of heat required to convert from water at 100 oC to steam at 100 oC = mHvap
Q4 = Amount of heat required to convert from steam at 100 oC to steam at 125 oC = mCm(steam)T3
Amount of heat energy,
Q = Q1 + Q2 + Q3 + Q4 + Q5
or, Q = mCm(ice)T1 + mHfus + mCm(water)T2 + mHvap + mCm(steam)T3
or, Q = [18.5 36.57 (0-(-10))] + [18.5 6.01 1000] + [18.5 75.40 (100-0)] + [18.5 40.67 1000] + [18.5 36.04 (125-100)]
or, Q = 6765.45 + 111185 + 139490 + 752395 + 16668.5
or, Q = 1026503.95 J
or, Q = 1026.5 kJ
Therefore, amount of energy = 1026.5 kJ