Question

In: Chemistry

When 1-­‐iodo-­‐1-­‐methylcyclohexane is treated with NaOCH2CH3 as the base, the more highly substituted alkene product predominates.When...

When 1-­‐iodo-­‐1-­‐methylcyclohexane is treated with NaOCH2CH3 as the base, the more highly substituted alkene product predominates.When KOC(CH3)3 is used as the base, the less highly substituted alkene predominates. Give the structures of the two products and offer an explanation.

Solutions

Expert Solution


Related Solutions

Give mechanism and product expected when 1-hexyne is treated with NaNH2 in liquid ammonia.
Give mechanism and product expected when 1-hexyne is treated with NaNH2 in liquid ammonia.
1. The possible components of your mixture are unreacted ferrocene and the substituted ferrocene product(s) of...
1. The possible components of your mixture are unreacted ferrocene and the substituted ferrocene product(s) of your reaction, which should travel the farthest up the TLC plate (highest Rf) and why? 2. Which should have a higher Rf value: the mono-substituted ferrocene or the di-substituted ferrocene? 3. In the column chromatography portion of your experiment next week, you use different solvents or solvent mixtures to elute the column for separation of your product mixture. Why is this required? Why use...
In acid-catalyzed addition of water to alkene, alcohol is the product.
  In acid-catalyzed addition of water to alkene, alcohol is the product. The conjugate base of the acid may compete with water for the newly formed carbocation and give a different product (other than alcohol). Among the following acids, which is the best acid catalyst? Which is the worst? Depend your answers.                HOAc     HCl      H2SO4       CF3COOH
Why are Not for Profit investments treated differently and why would they be more scrutinized when...
Why are Not for Profit investments treated differently and why would they be more scrutinized when compared to private companies?
Draw a diagram that illustrates the hyperconjugation that explains these phenomena: - more substituted alkenes have...
Draw a diagram that illustrates the hyperconjugation that explains these phenomena: - more substituted alkenes have lower heats of hydrogenation - more substituted carbocations are more stable - staggered conformations are lower in energy than eclipsed - allylic SN2 is faster than non-allylic Be sure to use shading to indicate the location of nodes and use arrows to show overlap. Thank you!!!
1) What alkene(s) will be produced when each of the following alcohols is dehydrated? 2- propanol...
1) What alkene(s) will be produced when each of the following alcohols is dehydrated? 2- propanol 2- butanol 2) Why is phosphoric acid preferred over sulfuric acid for dehydration of alcohols? 3) What measures should be taken if droplets of phosphoric acid are splashed in the eyes? 4) Give an example of a skeletal rearrangement during a dehydration experiment. 5) What is the purpose of adding anhydrous sodium sulfate to the dehydration product in experiment B?
Identify a product that is monopolisticly competitive. Specifically, define what products it could be substituted for...
Identify a product that is monopolisticly competitive. Specifically, define what products it could be substituted for and also what characteristics make is differentiated from those products. Discuss what the seller of the product could do to increase the differentiation of that product, and Discuss what impact increasing the differentiation of that product would likely have on the products price and the seller's profits earned from the product.
When ortho-bromonitrobenzene is treated with NaOH and heat one product is formed. a) show the mechanism...
When ortho-bromonitrobenzene is treated with NaOH and heat one product is formed. a) show the mechanism b) would the reaction occur if starting material was para-bromotoluene c) would the reaction occur if starting material was meta-bromotoluene
1. 1-methyl-1,2-epoxycyclohexane treated with 1) CH3MgBr and 2) H20 provides what product? 2. 1,5-epoxypentane treated with...
1. 1-methyl-1,2-epoxycyclohexane treated with 1) CH3MgBr and 2) H20 provides what product? 2. 1,5-epoxypentane treated with EXCESS HI provides what product?
1) What alkene(s) will be produced when each of the following alcohols is dehydrated? Cyclohexanol 2-methylcyclopentanol...
1) What alkene(s) will be produced when each of the following alcohols is dehydrated? Cyclohexanol 2-methylcyclopentanol 3-methylcyclopentanol 2,3-dimethyl-2-butanol 2) Illustrate the mechanism for the acid-catalyzed dehydration of cyclohexanol. 3) Illustrate the mechanism for the acid-catalyzed dehydration of 2-methylcyclohexanol. How many products are possible? 4) Write equations to illustrate the reaction of cyclohexene with KMnO4? 5) Given the following data, calculate the theoretical yield and percentage yield of cyclohexene: Cyclohexanol used: 20.0 mL Cyclohexene obtained: 12.0 g
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT