Question

In: Chemistry

Consider the following reaction at equilibrium. What effect will adding some C have on the system?...

Consider the following reaction at equilibrium. What effect will adding some C have on the system? CO2(g) + C(graphite) ⇌ 2 CO(g) Question 1 options: A) No effect will be observed since C is not included in the equilibrium expression. B) The equilibrium constant will decrease. C) The reaction will shift to the left in the direction of reactants. D) The equilibrium constant will increase. E) The reaction will shift to the right in the direction of products.

Solutions

Expert Solution

Consider the following reaction at equilibrium.

What effect will adding some C have on the system

CO2(g) + C(graphite) ⇌ 2 CO(g)

First, let us state the Le Chatelier principle which deals with changes in an equilibrium:

The statement is as follows:

If any equilibrium is disturbed, that is, change in conditions such as P,T, concentration, partial pressure, etc.., the system will counterbalance such change in order to favour the system's equilbirium.

  • Change in concentration
  • Change in pressure
  • Change in temperature

CO2(g) + C(graphite) ⇌ 2 CO(g)

A) No effect will be observed since C is not included in the equilibrium expression. TRUE

B) The equilibrium constant will decrease. --> Kc is constant and independent on concentrations

C) The reaction will shift to the left in the direction of reactants. --> False, since CO2 and CO are in equilibrium

D) The equilibrium constant will increase. --> false, Kc can't increase

E) The reaction will shift to the right in the direction of products. ---> false, no effect CO and CO2 re in equilbirum


Related Solutions

14-Consider the following reaction at equilibrium. What effect will increasing the temperature have on the system?...
14-Consider the following reaction at equilibrium. What effect will increasing the temperature have on the system? Why?             CO2(g) + 2 H2O(l) ⇌ CH4(g) + 2 O2(g)      ΔH° = +890 kJ 15-Consider the following reaction at equilibrium. What effect will decreasing the temperature have on the system? Why?             C3H8(g) + 5 O2(g) ⇌ 3 CO2(g) + 4 H2O(l)   ΔH° = -2220 kJ Coal, which is primarily carbon, can be converted to natural gas, primarily CH4, by the exothermic reaction:...
10- Describe Le Chatelier’s Principle 11-Consider the following reaction at equilibrium. What effect will reducing some...
10- Describe Le Chatelier’s Principle 11-Consider the following reaction at equilibrium. What effect will reducing some C have on the system? Why?             CO2(g) + C(graphite) ⇌ 2 CO(g) 12- Consider the following reaction at equilibrium. What effect will increasing the volume of the reaction mixture have on the system? Why?             CuS(s) + O2(g) ⇌ Cu(s) + SO2(g) 13-Consider the following reaction at equilibrium. What effect will reducing the volume of the reaction mixture have on the system? Why?...
Consider the equilibrium system described by the chemical reaction below. At equilibrium, a sample of gas...
Consider the equilibrium system described by the chemical reaction below. At equilibrium, a sample of gas from the system is collected into a 4.00 L flask at 600 K. The flask is found to contain 3.86 g of PCl₅, 12.7 g of PCl₃, and 13.3 g of Cl₂. What are the values of Kc and Kp for this reaction? PCl₅(g) ⇌ PCl₃(g) + Cl₂(g)
Consider the following reaction: A(g)⇌B(g)+C(g) Find the equilibrium concentrations of A, B, and C for each...
Consider the following reaction: A(g)⇌B(g)+C(g) Find the equilibrium concentrations of A, B, and C for each of the following different values of Kc. Assume that the initial concentration of A in each case is 1.0 M and that the reaction mixture initially contains no products. Make any appropriate simplifying assumptions. ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- Part A Kc= 1.8 Express your answer using two significant figures. Enter your answers numerically separated by commas. ------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Part B Kc= 1.0×10−2 Express your answer using two significant...
Consider the following reaction: A(g)⇌B(g)+C(g) Find the equilibrium concentrations of A, B, and C for each...
Consider the following reaction: A(g)⇌B(g)+C(g) Find the equilibrium concentrations of A, B, and C for each of the following different values of Kc. Assume that the initial concentration of A in each case is 1.0 M and that the reaction mixture initially contains no products. Make any appropriate simplifying assumptions. Part A: Kc= 1.0 Express your answer using two significant figures. Enter your answers numerically separated by commas. Part B: Kc= 2.0×10−2 Express your answer using two significant figures. Enter...
Consider the following system at equilibrium. S(s)+O2(g)<--->SO2(g) 1. How will adding more S(s) shift the equilibrium?...
Consider the following system at equilibrium. S(s)+O2(g)<--->SO2(g) 1. How will adding more S(s) shift the equilibrium? A) to the right B) to the left C) no effect 2. How will removing some SO2(g) shift the equilibrium? A) to the right B) to the left C) no effect 3. How will decreasing the volume of the container shift the equilibrium? A) to the right B) to the left C) no effect
What is meant by chemical equilibrium? Given the following reaction: A + B <--> C +D...
What is meant by chemical equilibrium? Given the following reaction: A + B <--> C +D (reversible reaction), how would you drive the following reaction away from equilibrium to produce more of substances A and B?
Predict and calculate the effect of concentration changes on an equilibrium system. Some SO2Cl2 is allowed...
Predict and calculate the effect of concentration changes on an equilibrium system. Some SO2Cl2 is allowed to dissociate into SO2 and Cl2 at 373 K. At equilibrium, [SO2Cl2] = 0.234 M, and [SO2] = [Cl2] = 0.136 M. Additional SO2 is added so that [SO2]new = 0.216 M and the system is allowed to once again reach equilibrium. SO2Cl2(g) SO2(g) + Cl2(g) K = 7.84×10-2 at 373 K (a) In which direction will the reaction proceed to reach equilibrium? (b)...
What would be the appropriate equilibrium temperature of a system obtained by adding 25.0 g of...
What would be the appropriate equilibrium temperature of a system obtained by adding 25.0 g of ice at 0°C to 250.0 mL of "hot" (80°C) coffee, assuming that the heat capacity and density of the coffee are the same as for pure water (4.18 J g-1 °C-1 and 0.997 g mL-1), and also assuming negligible heat transfer with the surroundings? [For water, ΔHfusion = 6.02 kJ/mol.]    *Note: the answer is 65 deg C
Consider the following reaction which is at equilibrium at 100°C: A(g) + B(g) ↔ AB (g)...
Consider the following reaction which is at equilibrium at 100°C: A(g) + B(g) ↔ AB (g) ΔH=420 kJ/mol Predict the direction where the reaction would proceed, and explain your reasoning: a. The reaction vessel were pressurized to 5atm with helium b. The temperature were increased to 200°C c. The reaction were coupled with another reaction: AB + D2 → AD + BD d. The volume of the reaction vessel were increased from 2.0L to 5.0L without removing any gas e....
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT