In: Chemistry
Hartree-Fock self-consistent field theory can deliver the best possible wavefunction for a multielectron atom.
The Hartee-Fock energy is always lower than the real energy by an amount that is referred to as the correlation energy.
According to Variation Theory, it is possible to compute a He energy of -86.7 eV.
Zeff is a parameter in the exact wavefunction of He.
The following wavefunction would be acceptable for a 2-electron system: [f(1)g(2)][α(1)β(2)-α(2)β(1)].
The Born-Oppenheimer approximation permits the separation of the electronic and nuclear components of
the wavefunction.
N2- is paramagnetic.
In HMO theory, the overlap integral assumption is accurate
1) Hartree-Fock self-consistent field theory can deliver the best possible wavefunction for a multielectron atom.
True : It gives the lowest possible total energy for a multi-electron system when combined into a Slater determinant and used with the complete multielectron Hamiltonian to calculate the expectation value for the total energy of the system.
2) The Hartee-Fock energy is always lower than the real energy by an amount that is referred to as the correlation energy : False
3) According to Variation Theory, it is possible to compute a He energy of -86.7 eV.
Flase : Its -77.37 ev
4) True
5)
The Born-Oppenheimer approximation permits the separation of the electronic and nuclear components of
the wavefunction
True : Born-Oppenheimer approximation shows how the electronic motions can be approximately separated from the nuclear motions
6) N2- is paramagnetic
True : As there is one unpaired electron in molecular orbital (antibonding) of N2- molecular ion
7)False , these are approximate