In: Chemistry
1. What is the mole fraction of O2 in a mixture of 5.07 g of O2, 7.16 g of N2, and 1.33 g of H2?
2. What is the mole fraction of N2 in a mixture of 5.07 g of O2, 7.16 g of N2, and 1.33 g of H2?
3. What is the mole fraction of H2 in a mixture of 5.07 g of O2, 7.16 g of N2, and 1.33 g of H2?
4. What is the partial pressure in atm of O2 of this mixture if it is held in a 12.50 −L vessel at 13 ∘C?
5. What is the partial pressure in atm of N2 of this mixture if it is held in a 12.50 −L vessel at 13 ∘C?
6. What is the partial pressure in atm of H2 of this mixture if it is held in a 12.50 −L vessel at 13 ∘C?
Answer - We are given, 5.07 g of O2, 7.16 g of N2, and 1.33 g of H2
First we need to calculate the moles of each
Moles of O2 = 5.07 g / 31.998 g.mol-1 = 0.158 moles
Moles of N2 = 7.16 g / 28.014 g.mol-1 = 0.256 moles
Moles of H2 = 1.33 g / 2.016 g.mol-1 = 0.660 moles
Now we need to calculate the total moles
Total moles = 0.158 + 0.256 + 0.660
= 1.07 moles
We know mole fraction formula
Moles fraction = moles / total moles
1) Moles fraction of O2 = 0.158 moles / 1.07 mole = 0.148
2) Moles fraction of N2 = 0.256 moles / 1.07 mole = 0.238
3) Moles fraction of H2 = 0.660 moles / 1.07 mole = 0.614
Now we need to calculate the total pressure from the total moles, volume and temperature given
Total moles = 1.07 moles , V = 12.50 L , T = 13 +273 = 286 K
Now using the Ideal gas law –
PV = nRT
P = nRT /V
= 1.07 moles * 0.0821 L.atm.mol-1.K-1*286 K / 12.50 L
= 2.02 atm
We know the formula
Mole fraction = partial pressure / total pressure
So, partial pressure = mole fraction * total pressure
4 ) Partial pressure of O2 = 0.148 * 2.02 atm = 0.298 atm
5) Partial pressure of N2 = 0.238 * 2.02 atm = 0.480 atm
6) Partial pressure of H2 = 0.614 * 2.02 atm = 1.24 atm