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1) Use the table below to answer the questions that follow. Thermodynamic Quantities for Selected Substances...

1) Use the table below to answer the questions that follow.

Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) __

Substance ΔH ° f (kJ/mol) ΔG ° f (kJ/mol) S (J/K-mol)

Calcium

Ca (s) 0 0 41.4

CaCl 2 (s) -795.8 -748.1 104.6

Ca 2 + (aq) 226.7 209.2 200.8

Chlorine

Cl 2 (g) 0 0 222.96

Cl- (aq) -167.2 -131.2 56.5

Oxygen

O 2 (g) 0 0 205.0

H 2O (l) -285.83 -237.13 69.91

Phosphorus

P 2 (g) 144.3 103.7 218.1

PCl 3 (g) -288.1 -269.6 311.7

POCl 3 (g) -542.2 -502.5 325

Sulfur

S (s, rhombic) 0 0 31.88

SO 2(g) -269.9 -300.4 248.5

SO 3(g) -395.2 -370.4 256.2

The value of ΔH° for the oxidation of solid elemental sulfur to gaseous sulfur dioxide,

S (s, rhombic) + O 2 (g) → SO 2 (g) is __________ kJ/mol.

a) +0.00

b) +11.6

c) +269.9

d) -11.6

e) -269.9

2) Use the table below to answer the questions that follow.

Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C)
__
Substance ΔH ° f (kJ/mol) ΔG ° f (kJ/mol) S (J/K-mol)
   
Calcium
Ca (s) 0 0 41.4
CaCl 2 (s) -795.8 -748.1 104.6
Ca 2+ (aq) 226.7 209.2 200.8

Chlorine  
Cl 2 (g) 0 0 222.96  
Cl- (aq) -167.2 -131.2 56.5

Oxygen  
O 2 (g) 0 0 205.0
H 2O (l) -285.83 -237.13 69.91

Phosphorus  
P 2 (g) 144.3 103.7 218.1
PCl 3 (g) -288.1 -269.6 311.7
POCl 3 (g) -542.2 -502.5 325

Sulfur  
S (s, rhombic) 0 0 31.88
SO 2(g) -269.9 -300.4 248.5
SO 3(g) -395.2 -370.4 256.2


The value of ΔG° at 25 °C for the oxidation of solid elemental sulfur to gaseous sulfur trioxide,

2S (s, rhombic) + 3O 2 (g) → 2SO 3 (g)

is __________ kJ/mol.

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