In: Other
1) Use the table below to answer the questions that follow.
Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) __
Substance ΔH ° f (kJ/mol) ΔG ° f (kJ/mol) S (J/K-mol)
Calcium
Ca (s) 0 0 41.4
CaCl 2 (s) -795.8 -748.1 104.6
Ca 2 + (aq) 226.7 209.2 200.8
Chlorine
Cl 2 (g) 0 0 222.96
Cl- (aq) -167.2 -131.2 56.5
Oxygen
O 2 (g) 0 0 205.0
H 2O (l) -285.83 -237.13 69.91
Phosphorus
P 2 (g) 144.3 103.7 218.1
PCl 3 (g) -288.1 -269.6 311.7
POCl 3 (g) -542.2 -502.5 325
Sulfur
S (s, rhombic) 0 0 31.88
SO 2(g) -269.9 -300.4 248.5
SO 3(g) -395.2 -370.4 256.2
The value of ΔH° for the oxidation of solid elemental sulfur to gaseous sulfur dioxide,
S (s, rhombic) + O 2 (g) → SO 2 (g) is __________ kJ/mol.
a) +0.00
b) +11.6
c) +269.9
d) -11.6
e) -269.9
2) Use the table below to answer the questions that
follow.
Thermodynamic Quantities for Selected Substances at 298.15 K (25
°C)
__
Substance ΔH ° f (kJ/mol) ΔG
° f (kJ/mol) S (J/K-mol)
Calcium
Ca (s) 0 0 41.4
CaCl 2 (s) -795.8 -748.1 104.6
Ca 2+ (aq) 226.7 209.2 200.8
Chlorine
Cl 2 (g) 0 0 222.96
Cl- (aq) -167.2 -131.2 56.5
Oxygen
O 2 (g) 0 0 205.0
H 2O (l) -285.83 -237.13 69.91
Phosphorus
P 2 (g) 144.3 103.7 218.1
PCl 3 (g) -288.1 -269.6 311.7
POCl 3 (g) -542.2 -502.5 325
Sulfur
S (s, rhombic) 0 0 31.88
SO 2(g) -269.9 -300.4 248.5
SO 3(g) -395.2 -370.4 256.2
The value of ΔG° at 25 °C for the oxidation of solid elemental
sulfur to gaseous sulfur trioxide,
2S (s, rhombic) + 3O 2 (g) → 2SO 3
(g)
is __________ kJ/mol.