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The solubility of barium carbonate, BaCO3, is 0.0100 g/L. Its molar mass is 197.3 g/mol. What...

The solubility of barium carbonate, BaCO3, is 0.0100 g/L. Its molar mass is 197.3 g/mol. What is the Ksp of barium carbonate?

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Expert Solution

              Solubility (s) of BaSO4 = 0.0100 g/ L = 0.0100/197.3 mol/L =     5.0 X 10-5 mol/L    

                                  BaSO4      <=======>   Ba2+       +       SO42-

Solubility (s):                  s mol/L                            s mol/L              s mol/L

Solubility product for this reaction: Ksp = [ Ba2+] X [SO42-]

or, Ksp = [s][s]

Ksp = s2

Ksp = [5 X 10-5]2

Ksp = 2.5 X 10-9


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