Write balanced half-reactions for the following redox
reaction:
8Fe+3(aq)+AsH3(g)+4H2O(l)? 8Fe+2(aq)+H3AsO4(aq)+8H+(aq)
I think red: 8Fe3+?8Fe2+(aq)+e- ox: 8e-...
Write balanced half-reactions for the following redox
reaction:
1. a) Show the balanced half reactions and the total balanced
reaction for the following redox reaction in acidic solution.
RuO4 + H2SeO3 → Ru3+ + SeO42-
b) Comment on whether you expect this reaction to be
spontaneous. Show all of your work.b
2 (a) Use the Lattimer diagram for chlorine in basic conditions
to determine the potential for reduction of ClO4- to Cl2 .
(b) Write a balanced equation for this half reaction
Problem 20.51
Given the following reduction half-reactions:
Fe3+(aq)+e??Fe2+(aq)
E?red=+0.77V
S2O2?6(aq)+4H+(aq)+2e??2H2SO3(aq)
E?red=+0.60V
N2O(g)+2H+(aq)+2e??N2(g)+H2O(l)
E?red=?1.77V
VO+2(aq)+2H+(aq)+e??VO2+(aq)+H2O(l)
E?red=+1.00V
Part A
Write balanced chemical equation for the oxidation of
Fe2+(aq) by S2O2?6 (aq).
Express your answer as a chemical equation. Identify all of the
phases in your answer.
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Part B
Calculate ?G? for this reaction at 298 K.
Express your answer using two significant figures.
?G? =
kJ
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Part C
Calculate the equilibrium constant K for this reaction...
Balance the following redox reactions. Show the complete
balanced reduction half and oxidation half reaction, and label each
accordingly. Give the complete balanced reaction.
A.) CN-1 + MnO4-2 --->
CNO-1 + MnO2
B.) S2O3-2 +
IO2-1 ---> I- +
S4O6-2
Write the balanced half-reaction for the following redox
reaction (include physical states like I did in final answer):
2CO2(g) + 12H+(aq) + 6Zn(s)
-----> C2H5OH(l) + 3H2O(l) +
6Zn2+(aq)
Balance the following redox reactions, in base, using the
half-reaction method. Clearly identify each balanced half-reaction
and the overall balanced equation.
C3H8O2 (a) + Cr2O72– (aq)  C3H4O4 (aq) + 2 Cr3+ (aq)
20#15
Given the following half-reactions and associated standard
reduction potentials:
AuBr−4(aq)+3e−→Au(s)+4Br−(aq)
E∘red=−0.858V
Eu3+(aq)+e−→Eu2+(aq)
E∘red=−0.43V
IO−(aq)+H2O(l)+2e−→I−(aq)+2OH−(aq)
E∘red=+0.49V
Sn2+(aq)+2e−→Sn(s)
E∘red=−0.14V
a) Write the cell reaction for the combination of these
half-cell reactions that leads to the largest positive cell
emf.
b) Calculate the value of this emf.
E∘max = _____ V
c) Write the cell reaction for
the combination of half-cell reactions that leads to the smallest
positive cell emf.
d) Calculate the value of
this emf.
E∘min = _____ V
An electrochemical cell is based on the following two
half-reactions:
Ox: Pb(s)?Pb2+(aq, 0.21M )+2e?
Red: MnO?4(aq, 1.25M )+4H+(aq,
2.5M )+3e??
MnO2(s)+2H2O(l). Compute the cell potential at 25
?C.
Exercise 18.62
Calculate E∘cell for each of the following
balanced redox reactions.
Part A
O2(g)+2H2O(l)+4Ag(s)→4OH−(aq)+4Ag+(aq)
Express your answer using two significant figures.
E∘cell =
V
Part B
Br2(l)+2I−(aq)→2Br−(aq)+I2(s)
Express your answer using two significant figures.
E∘cell =
V
Part C
PbO2(s)+4H+(aq)+Sn(s)→Pb2+(aq)+2H2O(l)+Sn2+(aq)
E∘cell = v
Calculate E∘cell for each of the following balanced
redox reactions. Are the reactions spontanous?
A) 2Cu(s)+Mn2+(aq)→2Cu+(aq)+Mn(s)
B) MnO2(s)+4H+(aq)+Zn(s)→Mn2+(aq)+2H2O(l)+Zn2+(aq)
C) Cl2(g)+2F−(aq)→F2(g)+2Cl−(aq)