In: Chemistry
How to use Le Chatelier's principle to predict the effect of a change in concentration on the equilibrium position and on K?
Le Chatelier's Principle: The dynamic equilibrium is disturbed by changing the conditions like concentration, pressure, temperature etc., the position of equilibrium moves to counteract the change.
Consider an equilibium reaction A+2B <===> C+D
the equilibrium constant K=[C][D]/[A][B]2
=> If you increase the concentration of A, the position of equilinrium will move to counteract means it will move so the concentration of A decreases again by reacting with B and forming C and D. The position of equilibrium moves to the right.
=> The value of K is increases as the [A] decreses because K is inversely proportional to [A].
=> If you decrease the concentration of A, the position of equilinrium will move to counteract means it will move so the concentration of A increases again. That means that more C and D will react to replace the A that has been removed.
=> The position of equilibrium moves to the left.
=> The value of K is decreases as the [A] decreses because K is inversely proportional to [A].