Question

In: Chemistry

Show your work! 1. How much energy is in a beta-Lyman emission of hydrogen? 2. The...

Show your work!

1. How much energy is in a beta-Lyman emission of hydrogen?

2. The gamma Lyman emission of hydrogen corresponds to an electron dropping from which energy level to which other energy level?

Solutions

Expert Solution

(1)Beta-Lyman emission occurs when the electron falls from the n = 3 orbital to the n = 1 orbital

From Rydburg's Equation , 1/ λ = R[(1/ni2) – (1/nf2)]
   Where R = Rydburg's constant = 10.96 x106 m-1
               λ = wavelength = ?
               ni = 1
               nf = 3
Plug the values we get λ = 1.026x10-7 m

Energy ,E = hc / λ

Where

h = plank's constant = 6.625x 10-34 Js

c = speed of light = 3x 108 m/s

λ = wave length = 1.026x10-7 m

Plug the values we get E = 1.94x10-18 J

(2)Gamma-Lyman emission occurs when the electron falls from the n = 4 orbital to the n = 1 orbital

From Rydburg's Equation , 1/ λ = R[(1/ni2) – (1/nf2)]
   Where R = Rydburg's constant = 10.96 x106 m-1
               λ = wavelength = ?
               ni = 1
               nf = 4
Plug the values we get λ = 9.732x10-8 m

Energy ,E = hc / λ

Where

h = plank's constant = 6.625x 10-34 Js

c = speed of light = 3x 108 m/s

λ = wave length = 9.732x10-8 m

Plug the values we get E = 2.042x10-18 J


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