In: Chemistry
At 1 atm, how much energy in kJ is required to heat 85.0 g H 2 O ( s ) at − 10.0 ∘ C to H 2 O ( g ) at 167.0 ∘ C? Use the heat transfer constants found in this table.
Quantity | per gram | per mole |
Enthalpy of fusion | 333.6 J/g | 6010. J/mol |
Enthalpy of vaporization | 2257 J/g | 40660 J/mol |
Specific heat of solid H2O (ice) | 2.087 J/(g·°C) * | 37.60 J/(mol·°C) * |
Specific heat of liquid H2O (water) | 4.184 J/(g·°C) * | 75.37 J/(mol·°C) * |
Specific heat of gaseous H2O (steam) | 2.000 J/(g·°C) * | 36.03 J/(mol·°C) * |
Q1= energy needed to warm the ice from -10 degree C to 0 degree C
Q1= mass of ice*specific heat of ice *temperature change
= (85 g)*(2.087 J/gC)*(10 degree C)= 1773.95 J
Q2= energy needed to phase change of H2O(from solid to liquid )
Q2= mass of H2O* latent heat of fusion of water
= (85 g)*(333.6 J/g)= 28356 J
Q3= energy needed to warm the water from 0 to 100 degree C
Q3= mass of water *specific heat of water *temperature change
= (85 g)*(4.184 J/gC)*(100)= 35564 J
Q4=energy needed to phase change of H2O( from liquid to vapour )
= mass of H2O*heat of vaporization of water
= (85 g )*(2257 J/g)= 191845 J
Q5= energy needed to raise the temperature of steam from 100 to 167degree C
= mass of H20* specific heat of water vapour *temperature change
= (85 g )*(2.0 J/gC)*(167-100) = 11390 J
Q= Q1+Q2+Q3+Q4+Q5
Q=1773.95 + 28356 + 35564 + 191845 + 11390 = 268928.95 J = 269 kJ