Question

In: Chemistry

The equilibrium constant for the reaction of fluorine gas with bromine gas at 300 K is...

The equilibrium constant for the reaction of fluorine gas with bromine gas at 300 K is 54.7 and the reaction is: Br2(g) + F2(g) ⇔ 2 BrF(g) What is the equilibrium concentration of fluorine if the initial concentrations of bromine and fluorine were 0.121 moles/liter in a sealed container and no product was present initially?

Solutions

Expert Solution

           Br2(g) + F2(g) ⇔ 2 BrF(g)

I         0.121    0.121         0

C         -x         -x             2x

E     0.121-x   0.121-x    2x

      Kc   = [BrF]2/[Br2][F2]

    54.7    = (2x)2 /(0.121-x)(0.121-x)

    54.7   = (2x/0.121-x)2

    7.34   = 2x/0.121-x

     2x     = 7.34(0.121-x)

     x = 0.095

   [F2] = 0.121-x = 0.121-0.095 = 0.026M

[Br2] = 0.121-x = 0.121-0.095 = 0.026M

   [BrF]   = 2x = 2*0.095              = 0.19M


Related Solutions

The equilibrium constant, K, for the following reaction is 2.3 x 10-4 at 300 °C: N2...
The equilibrium constant, K, for the following reaction is 2.3 x 10-4 at 300 °C: N2 (g) + C2H2 (g) ⇌ 2 HCN (g). Calculate the equilibrium concentration of HCN when 0.555 moles of N2 and 0.555 moles of C2H2 are introduced into a 0.500 L vessel at 300 °C.
The equilibrium constant for the reaction below is K = 0.36 at 400 K. If 1.5...
The equilibrium constant for the reaction below is K = 0.36 at 400 K. If 1.5 g of PCl5 was initially placed in a reaction vessel with a volume of 250 cm3, what is the molar concentration of each gas at equilibrium? What is Delta Gorxn for the reaction: PCl5 (g) à PCl3 (g) + Cl2 (g) - Please show all work.
The equilibrium constant, K , of a reaction at a particular temperature is determined by the...
The equilibrium constant, K , of a reaction at a particular temperature is determined by the concentrations or pressures of the reactants and products at equilibrium. For a gaseous reaction with the general form aA+bB⇌cC+dD the Kc and Kp expressions are given by Kc=[C]c[D]d[A]a[B]b Kp=(PC)c(PD)d(PA)a(PB)b The subscript c or p indicates whether K is expressed in terms of concentrations or pressures. Equilibrium-constant expressions do not include a term for any pure solids or liquids that may be involved in the...
Bromine chloride, BrCl, decomposes to form chlorine and bromine. At a certain temperature the equilibrium constant...
Bromine chloride, BrCl, decomposes to form chlorine and bromine. At a certain temperature the equilibrium constant for the reaction is 11.1 and the equilibrium mixture contains 4.00 mol Cl 2. How many moles of Br2 and BrCl are present in the equilibrium mixture?
Calculate the equilibrium constant at 298 K for the reaction of ammonia with oxygen to form...
Calculate the equilibrium constant at 298 K for the reaction of ammonia with oxygen to form nitrogen and water. The data refer to 298 K. 4NH3(g) + 3O2(g) <> 2N2(g) + 6H2O(l) Substance NH3(g) O2(g) N2(g) H2O(l) ΔH°f (kJ/mol) -46 0 0 -285 ΔG°f (kJ/mol) -16 0 0 -237 S°(J/K·mol) 192 205 192 70 I thought Kc is just Molar concentration of Products divide by Molar concentration on Reactants which would be 12 x 16 divide by 14 x 13...
For the reaction of dissolution of lithium sulfate in water the equilibrium constant is positive (K...
For the reaction of dissolution of lithium sulfate in water the equilibrium constant is positive (K > 1). Li2SO4(s) ⇌ 2 Li+(aq) + SO4-2(aq)   ΔrHo = -30.5 kJ/mol Which of the following statements is correct? A. You can dissolve a larger amount of lithium sulfate in hot water than in cold water. B. The entropy of the system increases when lithium sulfate dissolves in water. C. The reaction as written is not spontaneous at standard conditions. D. Dissolution of lithium...
1)The equilibrium constant, Kp, for the following reaction is 0.497 at 500 K: PCl5(g) The equilibrium...
1)The equilibrium constant, Kp, for the following reaction is 0.497 at 500 K: PCl5(g) The equilibrium constant, Kp, for the following reaction is 0.497 at 500 K: PCl5(g) <------ ------> PCl3(g) + Cl2(g) Calculate the equilibrium partial pressures of all species when PCl5(g) is introduced into an evacuated flask at a pressure of 1.14 atm at 500 K. PPCl5 = atm PPCl3 = atm PCl2 = atm 2) The equilibrium constant, Kp, for the following reaction is 55.6 at 698...
The equilibrium constant, K, of a reaction at a particular temperature is determined by the concentrations or pressures of the reactants and products at equilibrium.
  The equilibrium constant, K, of a reaction at a particular temperature is determined by the concentrations or pressures of the reactants and products at equilibrium. For a gaseous reaction with the general form aA+bB⇌cC+dD the Kc and Kp expressions are given by Kc=[C]c[D]d/[A]a[B]b Kp=(PC)c(PD)d(PA)a(PB)b The subscript c or p indicates whether K is expressed in terms of concentrations or pressures. Equilibrium-constant expressions do not include a term for any pure solids or liquids that may be involved since their...
The equilibrium constant, K, for the following reaction is 10.5 at 350 K. 2CH2Cl2(g) CH4(g) +...
The equilibrium constant, K, for the following reaction is 10.5 at 350 K. 2CH2Cl2(g) CH4(g) + CCl4(g) An equilibrium mixture of the three gases in a 1.00 L flask at 350 K contains 5.47×10-2 M CH2Cl2, 0.177 M CH4 and 0.177 M CCl4. What will be the concentrations of the three gases once equilibrium has been reestablished, if 3.44×10-2 mol of CH2Cl2(g) is added to the flask? [CH2Cl2] =_____ M [CH4] = ________M [CCl4] =________ M
The equilibrium constant, K, for the following reaction is 10.5 at 350 K. 2CH2Cl2(g) =CH4(g) +...
The equilibrium constant, K, for the following reaction is 10.5 at 350 K. 2CH2Cl2(g) =CH4(g) + CCl4(g) An equilibrium mixture of the three gases in a 1.00 L flask at 350 K contains 5.12×10-2 M CH2Cl2, 0.166 M CH4 and 0.166 M CCl4. What will be the concentrations of the three gases once equilibrium has been reestablished, if 0.121 mol of CH4(g) is added to the flask? [CH2Cl2] = _________M [CH4] = _________ M [CCl4] = _________ M
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT