Question

In: Chemistry

The pH of a 0.392 M solution of the conjugate base, A-, of a weak acid,...

The pH of a 0.392 M solution of the conjugate base, A-, of a weak acid, HA, is 11.60. What is the Kb for A-?

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Expert Solution

pH = 11.60

[ A- ] = 0.392 M

[H+] = 10^-pH

          = 10^-11.60

           = 2.5 x 10^-12 M

[OH-] = 1.0 x 10^-14 / 2.5 x 10^-12 = 4 x 10^-3 M

A-   + H2O   ---------------------> AH + OH-

0.392                                        0          0

0.392-x                                     x           x

x = [OH-] = 4 x 10^-3 M

Kb = x^2 / 0.392 -x

kb = (4 x 10^-3)^2 / (0.392 - 4 x 10^-3)

Kb = 4.12 x 10^-5


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