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Methane at 25°C is burned in a boiler furnace with 10.0% excess air. The air enters the burner at a temperature of 100°C. Ninety percent of the methane fed is consumed; the product gas is analyzed and found to contain 10.0 mol CO2 per 1 mol of CO. The exhaust gases exit the furnace at 400°C. Calculate the rate of heat transferred from the furnace, given that a molar flow rate of 100 mol/s CH4 is fed to the furnace.
Cp/R = A +BT +CT2 + DT-2 Where T is in K from 298 oK |
Name | Chemical formula | Tmax | CpigP298/R | A | B*103 | C*106 | D*10+5 |
Methane | CH4 | 1500 | 4.217 | 1.702 | 9.081 | -2.164 | 0 |
Carbon monoxide | CO | 3000 | 3.507 | 3.376 | 0.557 | 0 | -0.031 |
Carbon dioxide | CO2 | 2500 | 4.467 | 5.457 | 1.045 | 0 | -1.157 |
Nitrogen | N2 | 2000 | 3.502 | 3.28 | 0.593 | 0 | 0.04 |
Oxygen | O2 | 2000 | 3.535 | 3.639 | 0.506 | 0 | -0.227 |
Water | H2O | 2000 | 4.038 | 3.47 | 1.45 | 0 | 0.121 |
Compound | F1 | HF1 | F1*HF1 |
O2 | 220 | 2375.001 | 522500.2 |
N2 | 827.62 | 2169.356 | 1795402 |
Total | 2317903 | ||
Compound | F1 | HF1 | F1*HF1 |
CH4 | 10 | 17385.93 | 173859.3 |
C0 | 81.82 | 11368.9 | 930203.2 |
CO2 | 8.18 | 18595.83 | 152113.9 |
N2 | 827.62 | 11124.1 | 9206529 |
O2 | 68.63 | 12111.64 | 831222.2 |
H20 | 180 | 13014.09 | 2342536 |
Total | 13636464 |