Question

In: Chemistry

Consider a CSTR used to carry out a reversible isomerization reaction (A↔B) where both the forward...

Consider a CSTR used to carry out a reversible isomerization reaction (A↔B) where both the forward and reverse reactions are first-order. Feed is pure A and the reaction is assumed to be elementary. CPa =1255 J/moleºK CPb = 1172 J/moleºK kf = 8.83 x 104 e –6290/T sec-1 kr = 4.17 x 1015 e –14947/T sec-1 where T is in degrees Kelvin (a) Is the reaction exothermic or endothermic? What is the standard enthalpy change for the reaction? (b) What is the equilibrium fraction conversion at 340ºK? (c) What conversion is achieved if t = 480 sec and the reactor temperature is 340ºK? (d) For t = 480 sec, sketch the curve of fraction conversion versus reactor temperature over the range 320 to 370ºK. (e) Derive the equation for the curve describing the energy balance on the CSTR for adiabatic operation. Substitute variables into this expression to obtain a relation between X, Tinlet , and Toutlet. (f) In order to maximize production of B when t = 480 sec, what inlet temperature should be specified?

Solutions

Expert Solution


Related Solutions

Consider the gas phase reversible reaction 2A ↔ B that occurs at atmospheric pressure. a) If...
Consider the gas phase reversible reaction 2A ↔ B that occurs at atmospheric pressure. a) If the equilibrium constant Ka = 0.1, what are the equilibrium mole fractions of A and B? b) Assuming the reaction is elementary, write the rate law using kA and k-A as the forward and reverse rate constants, respectively. What is the equilibrium constant Kc in terms of kA and k-A? Assuming an ideal gas system, write an expression for Ka in terms of kA...
Consider the following reaction: S↔P where the rate constant for the forward reaction is k1, and...
Consider the following reaction: S↔P where the rate constant for the forward reaction is k1, and the rate constant for the reverse reaction is k2, and Keq= [P]/[S] Which of the following would be affected by an enzyme? Please answer yes or no and give a short explanation (5-20 words maximally) a) decreased Keq b) increased k1 c) increased Keq d) increased Δ G# e) decreased Δ G# f) increased k2 g) more negative Δ G0
An elementary reaction A+B  C+D is to be carried out in a non-ideal CSTR which...
An elementary reaction A+B  C+D is to be carried out in a non-ideal CSTR which has both bypassing and a stagnant region in this reactor. The measured reactor volume is 1.0 m3 and the flow rate to the reactor is 0.1 m3/min. The reaction rate constant is 0.28 m3/kmol.min. The feed is equimolar in A and B with an entering concentration of A equal to 2.0 kmol/m3 k. Calculate the conversion that can be expected in this reactor if...
Reagent A undergoes an essentially irreversible isomerization reaction that obeys first-order kinetics. A --> B Both...
Reagent A undergoes an essentially irreversible isomerization reaction that obeys first-order kinetics. A --> B Both A and B are liquids at room temperature and both have extremely high boiling points. Pure A at 20oC is fed into the reactor. Data: Reaction rate expression: r = k.CA Rate constant at 163 °C = 0.8 hr-1 Activation energy = 30,000 cal/gmole Heat of reaction = — 83 cal/g Molecular weight = 250 CpA=CpB=0.5 cal/g.oC pA=pB= 0.9 g/cm3 a) Determine the CSTR...
Consider a CSTR where a simple first-order reaction takes place. The rate constant depends on the...
Consider a CSTR where a simple first-order reaction takes place. The rate constant depends on the reactor temperature and can be given the Arrhenius equation. The reactor contents are cooled by a coolant that flows through a jacket around the reactor. Derive the dynamic model of the CSTR. i.e. the change of concentration of component A and the temperature of the reactor, assuming the flow rate and the inlet conditions are constant. You can use linearization technique for this coupled...
Consider the reaction A ⇌ B which is exothermic in the forward direction. Which of the...
Consider the reaction A ⇌ B which is exothermic in the forward direction. Which of the following increase(s) when the temperature increases. You may select more than one, or none, of the options. (a) Ea (reverse) (b) the forward rate (c) Ea (forward) (d) the reverse rate
Consider the reaction A ⇌ B which is endothermic in the forward direction. Which of the...
Consider the reaction A ⇌ B which is endothermic in the forward direction. Which of the following increase(s) when the temperature increases. (You may select more than one answer.) (a) Earev (b) Eafor (c) the forward rate (d) the reverse rate (e) the equilibrium constant
A coffee-cup (constant pressure) calorimeter is used to carry out the following reaction in an unknown...
A coffee-cup (constant pressure) calorimeter is used to carry out the following reaction in an unknown volume of water (where X is a hypothetical metal): X + 2 H2O → X(OH)2 + H2 In this process, the water temperature rose from 25.0 °C to 32.2 °C. If 0.00803 mol of "X" was consumed during the reaction, and the ΔH of this reaction with respect to the system is -1798 kJ mol-1 , what volume of water (in mL) was present...
Consider the following reaction which is at equilibrium at 100°C: A(g) + B(g) ↔ AB (g)...
Consider the following reaction which is at equilibrium at 100°C: A(g) + B(g) ↔ AB (g) ΔH=420 kJ/mol Predict the direction where the reaction would proceed, and explain your reasoning: a. The reaction vessel were pressurized to 5atm with helium b. The temperature were increased to 200°C c. The reaction were coupled with another reaction: AB + D2 → AD + BD d. The volume of the reaction vessel were increased from 2.0L to 5.0L without removing any gas e....
Consider the following set of three reversible elementary reactions: R1:O2 + M ↔ O + O...
Consider the following set of three reversible elementary reactions: R1:O2 + M ↔ O + O + M R2: O2 + O↔ O3 R3: O + O3↔ O2 + O2 Write expressions for the time-rate-of-change of molar concentration of the four species O, O2, O3, and M for this reaction set. Your expressions should be in terms of the molar concentrations of the four species involved in the reactions, and the forward and reverse rates for the three reactions.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT