Question

In: Chemistry

given that 16.0g of MnO2 and 30,0g of HCl react according to: MnO2 + 4HCl --->...

given that 16.0g of MnO2 and 30,0g of HCl react according to: MnO2 + 4HCl ---> MnCl2 + Cl2 + 2H20 a: what is the limiting reagent? b: what mass of MnCl2 could be produced? c: how much of each reagent remains when the reaction is complete? d. assuming a % yeild of 71.2%, caculate the auctual yeild of McCl2

Solutions

Expert Solution

a) molar mass of MnO2 = 86.9368 gm/mole

molar mass of HCl = 36.46094 gm/mol then 4 mole of HCl = 36.46094 4 = 145.84376 gm

According to reaction 1 mole of MnO2 react with 4 mole of HCl that mean 86.9368 gm MnO2 react with 145.84376 gm of HCl then to react with 16 gm of MnO2 required HCl = 145.84376 16 / 86.84376 = 26.87 gm

but HCl given 30 gm therefore HCl is excess ragent and MnO2 is limiting reagent

b) molar mass of MnCl2 = 125.844 gm/mol

According to reaction 1 mole of MnO2 produce 1 mole of MnCl2 that mean 86.84376 gm of MnO2 produce 125.844 gm of MnCl2 then 16 gm MnO2 produce 125.844 16 /86.84376 = 23.185 gm of MnCl2 produced.

c)

according to reaction 1 mole of MnO2 react with 4 mole of HCl that mean 86.9368 gm MnO2 react with 145.84376 gm of HCl then to react with 16 gm of MnO2 required HCl = 145.84376 16 / 86.84376 = 26.87 gm

but HCl given 30 gm therefore HCl is excess ragent and MnO2 is limiting reagent

HCl remain after complete reaction = 30.0 - 26.87 = 3.13 gm

d)23.185 gm of MnCl2 = 100% yield then 71.2% = 71.2 23.185 / 100 = 16.51 gm is actual yield


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