In: Chemistry
Expt. 11/11x: Identification of an Unknown Carbonyl Compound by Infrared Spectroscopy
1. What is the unsaturation number for each of the following: C5H9BrO and C7H13NO.
ALDEHYDE |
Aldehyde are having two weak absorptions to the right of the C-H stretch near 2850 cm-1 and 2750 cm-1 and are caused by the C-H bond that is part of the CHO aldehyde functional group. And carbonyl band around 1740-1720 cm-1. |
KETONE |
The weak aldehyde CH absorption bands will be absent.And carbonyl CO band around 1725-1705 cm-1. |
Degree of Unsaturation:
A compound with formula CaHbNcOdXe
where X is F, Cl, Br or I, and Ignore the Oxygen Molecules.
The degree of unsaturation is given by:
degree of unsaturation = 1/2 (2 + 2a - b + c - e).
C5H9BrO In this compound No. of C atoms (a) =5
No. of H atoms (b) =9
No. of Br atoms (e) =1 and substitute the values above formula,
degree of Unsaturation = 1/2 (2 + 2a - b + c - e)
=1/2(2+2*5-9-1)=1
degree of Unsaturation = 1
C7H13BNO In this compound No. of C atoms (a) =7
No. of H atoms (b) =13
No. of N atoms (c) =1 and substitute the values above formula,
degree of Unsaturation = 1/2 (2 + 2a - b + c - e)
=1/2(2+2*7-13+1)=2
degree of Unsaturation = 2