In: Chemistry
Given the data tables below for the concentrations of crystal violet dye in the crystal violet-hydroxide reaction CV+ + NaOH- --> CVOH + Na, calculate the order of hydroxide if the order of crystal violet is first order (ln[A] shows a linear relationship for CV).
CV+ + OH- --> CVOH
Data
Trial 1: CV + 0.020M NaOH |
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Time (s) |
%TCV |
[A]CV |
ln[A]CV |
1/[A]CV |
190 |
49.8 |
0.303 |
-1.195 |
3.303 |
250 |
52.6 |
0.279 |
-1.276 |
3.584 |
310 |
55.8 |
0.253 |
-1.373 |
3.947 |
370 |
58.4 |
0.234 |
-1.454 |
4.281 |
430 |
61.2 |
0.213 |
-1.545 |
4.689 |
490 |
63.8 |
0.195 |
-1.634 |
5.123 |
Trial 2: CV + 0.040M NaOH |
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Time (s) |
%TCV |
[A]CV |
ln[A]CV |
1/[A]CV |
180 |
54.8 |
0.261 |
-1.342 |
3.828 |
240 |
59.6 |
0.225 |
-1.493 |
4.449 |
300 |
64.2 |
0.192 |
-1.648 |
5.196 |
360 |
68.4 |
0.165 |
-1.802 |
6.063 |
420 |
72.2 |
0.141 |
-1.956 |
7.069 |
480 |
75.8 |
0.120 |
-2.118 |
8.310 |