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How could engineers and others ensure that a nuclear waste repository is safe from a) physical disturbances and b) human intrusion for the next million years?
Exempt waste and very low-level waste (VLLW) contains radioactive materials at a level which is not considered harmful to people or the surrounding environment. It consists mainly of demolished material (such as concrete, plaster, bricks, metal, valves, piping, etc.) produced during rehabilitation or dismantling operations on nuclear industrial sites. Other industries, such as food processing, chemical, steel, etc., also produce VLLW as a result of the concentration of natural radioactivity present in certain minerals used in their manufacturing processes (see also information page on Naturally-Occurring Radioactive Materials). The waste is therefore disposed of with domestic refuse, although countries such as France are currently developing specifically designed VLLW disposal facilities.
All toxic waste needs be dealt with safely – not just radioactive waste – and in countries with nuclear power, radioactive waste comprises a very small proportion of total industrial hazardous waste generated.
Radioactive waste is not unique to the nuclear fuel cycle. Radioactive materials are used extensively in medicine, agriculture, research, manufacturing, non-destructive testing, and minerals exploration. Unlike other hazardous industrial materials, however, the level of hazard of all radioactive waste – its radioactivity – diminishes with time
Like all industries, the generation of electricity produces waste. Whatever fuel is used, the waste produced in generating electricity must be managed in ways that safeguard human health and minimise the impact on the environment.
For radioactive waste, this means isolating or diluting it such that the rate or concentration of any radionuclides returned to the biosphere is harmless. To achieve this, practically all radioactive waste is contained and managed, with some clearly needing deep and permanent burial. From nuclear power generation, unlike all other forms of thermal electricity generation, all waste is regulated – none is allowed to cause pollution.
Nature has already proven that geological isolation is possible through several natural examples (or 'analogues'). The most significant case occurred almost 2 billion years ago at Oklo, in what is now Gabon in West Africa, where several spontaneous nuclear reactors operated within a rich vein of uranium ore. (At that time the concentration of U-235 in all natural uranium was about 3%.) These natural nuclear reactors continued for about 500,000 years before dying away. They produced all the radionuclides found in HLW, including over 5 tonnes of fission products and 1.5 tonnes of plutonium, all of which remained at the site and eventually decayed into non-radioactive elements.4
The study of such natural phenomena is important for any assessment of geologic repositories, and is the subject of several international research projects.
Electricity generation
In terms of radioactivity, the major source arising from the use of nuclear reactors to generate electricity comes from the material classified as HLW. Highly radioactive fission products and transuranic elements are produced from uranium and plutonium during reactor operations, and are contained within the used fuel. Where countries have adopted a closed cycle and reprocess used fuel, the fission products and minor actinides are separated from uranium and plutonium and treated as HLW (see below). In countries where used fuel is not reprocessed, the used fuel itself is considered a waste and therefore classified as HLW.
LLW and ILW is produced as a result of general operations, such as the cleaning of reactor cooling systems and fuel storage ponds, and the decontamination of equipment, filters, and metal components that have become radioactive as a result of their use in or near the reactor.
Reprocessing of used fuel
Any used fuel will still contain some of the original U-235 as well as various plutonium isotopes which have been formed inside the reactor core, and U-238. In total these account for some 96% of the original uranium and over half of the original energy content (ignoring U-238). Used nuclear fuel has long been reprocessed to extract fissile materials for recycling and to reduce the volume of HLW (see also information page on Processing of Used Nuclear Fuel). Several European countries, as well as Russia, China, and Japan have policies to reprocess used nuclear fuel.