Question

In: Chemistry

Short Answer Questions. a) Predict the effect (increase, decrease, no change) on the alkalinity of a...

Short Answer Questions.

a) Predict the effect (increase, decrease, no change) on the alkalinity of a natural water upon addition of the following compounds. Explain your answers:
i. CO2
ii. HNO3
iii. CdCl2
iv. NH3
v. Sulphate reduction (SO42- H2S)

Solutions

Expert Solution

Answer:

Alkalinity:

It is the measure of the Basicity of the water or the solution.

(or) It is the measure of the amount of the chemical bases. (or) Measure of the PH of the water or solution.

i) CO2 - Decreases

Explanation:

It is acidic in nature and forms Carbonic acid in the water. Hence the Acidic nature increases and Alkanity decreases.

H2O + CO2 H2CO3

It shows the lower PH value.

ii) HNO3 - Decreases

Explanation:

It is the strong acid the Alkanity of the water decreases and the Acidity increases.

iii) CdCl2 - No change

Explanation:

It is the neutral compound. Hence the Alkanity of the water can not change.


iv) NH3 - Increases.

Explanation:

Ammonia gas dissolves in the water due to the formation of the H-bonds. It is the Basic nature and forms the Ammonia solution.

Hence the Alkanity of the water increases.

NH3 + H2O NH4OH

v) Sulphate reduction (SO2-4  H2S) - Decreases

Explanation:

H2S is the gas and it is Acidic in nature. It dissolves in the water and the water becomes as a acidic solution. Hence the Alkanity of the water decreases.


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